Chemical changes Flashcards
What is Electrolysis?
the breaking down of a substance using electricity. An electric current is passed through an electrolyte causing it to decompose.
What is an Electrolyte?
a molten or dissolved ionic compound
What is oxidation and reduction?
oxidation: loss of electrons
reduction: gain of electrons
occurs in electrolysis
What is the symbol for oxidation?
->e^-
What is the symbol for reduction?
+e^-
Where do the positive ions (cations) in the electrolyte move?
Towards the cathode (negative electrode) and are reduced (gains electrons)
Where do the Negative ions (anions) in the electrolyte move?
towards the anode (positive electrode) and are oxidised (lose electrons).
What is an electrochemical cell?
a circuit, made up of the anode, cathode, electrolyte, a power source and the wires that connect the two electrodes
If your electrolyte is a solution:
1) Get two inert electrodes, e.g. graphite
2)Place both electrodes into a beaker filled with your electrolyte.
3)Connect the electrodes to a power supply using crocodile clips and wires
If your Electrolyte is a Molten Ionic substance:
1) Put your solid ionic substance in a crucible
2)Heat the crucible with a bunsen burner until the solid’s molten.
3)Once the solid’s molten, dip two clean, inert electrodes into the electrolyte.
4) Connect electrodes to a power supply using wires and clips.
How many sets of ions are in Molten ionic solids?
2
1 positve and 1 negative
Why can’t ionic solid be electrolysed?
ions are in fixed positions and can’t move.
Why can molten ionic compounds be electrolysed?
ions can move freely and conduct electricity
What happens to positive metal ions at the cathode?
reduced to metal atoms
What happens to Negative ions at the anode?
are oxidised to atoms or molecules
How many sets of ions are there in Aqueous solutions? why?
4
2 positive and 2 negative
Electricity splits water into:
Hydrogen ions H+
Hydroxide ions OH-
What happens at the cathode during electrolysis of Aqueous solution?
If metal ion is LESS reactive than hydrogen, it will be the one that will gain electrons and turn to the atom.
If metal ion is MORE reactive than the hydrogen, it is the H+ ion that gains electrons and turns to hydrogen gas.
What happens at the anode during electrolysis of Aqueous solution?
If negative ion is above OH-, it will be the one turn to atom.
If negative ion is below OH-, the OH- turns to oxygen gas and water.
What are the four different ions a solution of copper contains?
Cu2+, So4 2-, H+ and OH-
What happens when you electrolyse copper sulfate solution with inert electrodes?
Copper is less reactive than hydrogen, so copper metal is produced at the cathode.
Sulfate is below Hydroxide, so oxygen and water are produced at the anode.