Chemical Bonding Flashcards
What atoms have an expansion of the octet rule?
third row periodic table and beyond can access d orbitals
How does electronegativity flow through periodic table?
increases going up and going left to right (most significant)
What is VSEPR theory?
Walence-Shell Electron-Pair Repulsion model
electron groups repel one another and stay as far apart as possible thus causing molecules to assum especific shapes
How do you determine steric number for electron geometry?
number od position occupied by lone pairs and atoms
What is shape of molecule with 2 electron groups?
Linear, Linear 180
What is shape of molecule with 3 electron groups?
Trigonal planar, trigonal planar or bent 120/<120
What is shape of molecule with 4 electrong groups
tetrahedral, tetrahedral or trigonal pyramidal or bent, 109.5/<109.5
WHat is shape of molecule with 5 electron groups?
trigonal bipyramidal
What are bond angles for molecular geometry of trigonal bipyramidal or seesaw?
120 equatorial
90 axial
What is the bond angle in T-shaped (trigonal bipyramidal)?
<90
WHat is the bond angle in linear (trigonal bipyramidal)?
180
What is hsape of molecule with 6 ekectron groups?
Octahedral, octahedral or square pyramidal, or square planar, 90,<90,90
How do double and triple bonds effect repulsion?
creates a larger repulsive effect