chemical bonding Flashcards

1
Q

what are gas clouds made up of

A

a mixture of atoms and molecules together with the dust of solid material from old stars

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

how are gas clouds detected

A

by radio and infrared telescopes on Earth and by spectroscopic instruments carried by rockets

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what do all noble gases have

A

a full outermost shell of electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

how do other elements try achieving a full stable shell of electrons

A

by losing or gaining electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

what does ionic bonding involve

A

metals reacting with non metals

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

when are ions formed

A

if the overall energy change when metals react with non metals is favourable

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what happens in ionic bonding

A

electrons are transferred from the metal atoms to the non metal atoms giving the metal and non metal a stable electronic configuration of a noble gas

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

how are the ions held

A

by electrostatic attraction between oppositely charged ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

what do sodium and chlorine form

A

sodium chloride

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

what is an ionic bond

A

the bond between oppositely charged ions that attract each other strongly

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

how does a giant lattice form

A

in the solid compound each ion attracts many others of opposite charges to build up a lattice

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

what ions do group 1 elements form

A

+1 ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

what ions do group 2 elements form

A

+2 ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what ions do group 3 elements form

A

+3 ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what ions do group 6 elements form

A

-2 ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what ions do group 7 elements form

A

-1 ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

write the formula for chromium (III) hydroxide

A
  • identify the atoms and charges a compound is made of - chromium (III) hydroxide is made of chromium (III) ions (Cr3+) and hydroxide ions (OH-)
  • work out the formulas so the charges balance - to balance the +3 charge you need 3 -1 charges
  • Cr(OH)3
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

why don’t non metallic elements form ions when they react

A

it isn’t energetically favourable to form ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

what happens when non metals react

A

electrons are shared between atoms of the element

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

what is covalent bonding

A

sharing of electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

what is the result of covalent bonding

A

the resulting compound is mroe stable than the individual elements. shared electrons count as part of the outer shell of both atoms in the bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

what are covalent bonds

A

bonds formed by sharing electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

how are the two atoms held together in covalent bonding

A

the positively charged nuclei are simultaneously attracted to the negatively charged shared electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

what happens when electrons are shared

A

the atoms acheive more stable electrons

25
what are bonding pairs
electron pairs which form bonds
26
what are lone pairs
pairs of electrons not involved in bonding
27
whats a double bond
when two pairs of electrons form a covalent bond e.g. oxygen and carbon dioxide
28
whats a triple bond
when three pairs of electrons form a covalent bond e.g. nitrogen and hydrogen cyanide
29
what are the three types of covalently bonded structures
- polymers - simple molecular structures - covalent network structures
30
describe the bonding in carbon monoxide
involves a triple bond. two of the pair of electrons are formed by the carbon and oxygen atoms each contributing one electron to the pair (ordinary covalent bonds) however both electrons in the 3rd pair come from the oxygen atom (dative covalent bond)
31
what is a dative covalent bond
both bonding electrons come from the same atom.
32
how is a dative bond shown
by an arrow, it points away from the atom that is donating the pair of electrons
33
how are the hydrogen atoms in a hydrogen molecule held together
their nuclei are both attracted to the shared electrons. both atoms are identical so the electrons are all shared equally
34
what is the atomic core made up of
everything except the outer electrons
35
what are the atomic cores attracted to in all atoms
to the shared electron pairs
36
what is the charge of the atomic core of fluorine
Fluorine (2,7) nucleus has a charge of +9 (has 9 protons) innermost shell has a charge of -2 (2 electrons in the 1st shell) the core has a charge of 7+ (9-2=7)
37
how is the F2 molecule held together
the 7+ core charges are attracted to the negative charges on the shared electrons.
38
what is often the case with atoms bonded together
they're often different sizes.
39
which are more attracted to the shared electrons - the smaller or bigger atom
the core of the smaller atom will be closer to the shared electrons and will exert a stronger pull on them.
40
which atoms are also strongly attracted to the shared electrons
atoms with a greater core charge
41
how do atoms attract bonding electrons
unequally
42
why do atoms get a slightly positive or negative charge
one atom gets a slightly negative charge because it has a greater share of the bonding electrons. the other atom becomes slightly positively charged because it has lost its share in the bonding electrons
43
what are slightly positive and slightly negative bonds called
polar bonds
44
why is the O-H covalent bond polar
the two electrons in the bond are drawn closer to the oxygen atom athan the hydrogen atom
45
what do metals and non metals form
ionic compounds
46
what do non metals form
covalent compounds
47
what do metals form
metallic compounds
48
what is electronegativity
a measure of the ability of an atom in a molecule to attract electrons towards it. it measures an atoms attraction for bonding electrons
49
an atom is highly electronegative if...
it has strong electron pulling powers in covalent bonds
50
which atoms are more electronegative
if you exclude the noble gases the elements are more electronegative at the top of the group and at the RHS of the periodic table.
51
what do highest electronegativities correspond with
reactive non metals with small atoms
52
what do lowest electronegativites correspond with
reactive metals with large atoms
53
describe polar bonds
they're like covalent bonds with a bit of ionic character in them. ionic and covalent bonds are extreme forms of bonding - polar bonds are in between the two.
54
the bigger the difference in electronegativity between the atoms ....
.... the more polar the bond and the greater the ionic character
55
how do metal atoms acheive a full outer electron shell
metal atoms lose their outer electrons to form a lattice of regularly spaced positive ions. the outer electrons contribute to a sea of delocalised electrons which move freely through the lattice of cations
56
what is each positively charged ion in the metal attracted to
the negatively charged delocalised electrons
57
what is a metallic bond
the electrostatic attraction between the cations and the delocalised electrons
58
what does the strength of the metallic bond depend on
the number of electrons per atom available for delocalisation
59
more electrons lost =
= a more stronger bond