chemical bonding Flashcards

1
Q

what types of bonds do diatomic elements make?

A

pure covalent/ non-polar-covalent

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2
Q

what type of model in metallic bonding?

A

sea of electrons (free electron model)

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3
Q

conductivity, thermal conductivity and hardness…

A

increase moving across a period

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4
Q

structure of ionic bond

A

lattice (crystal)

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5
Q

EN for ionic bonds

A

Delta EN > 1.7

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6
Q

are ionic bonds brittle or soft?

A

brittle

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7
Q

define intramolecular forces

A

forces within molecule/element interaction

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8
Q

Define intermolecular forces

A

forces between molecules

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9
Q

do covalent bonds conduct electricity?

A

no with the exception of acids and bases

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10
Q

EN for polar

A

EN = 0.5 - 1.7

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11
Q

EN for non-polar

A

EN < 0.5

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12
Q

when does the central atom have more than 8 valence electrons?

A

PCl5 and XeF4-

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13
Q

when does the central atom have less than 8 valence electrons?

A

BH3-

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14
Q

when does a molecule contain an odd number of non-bonding electrons?

A

NO

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15
Q

what is a cordinate covalent bond?

A

when both electrons in the bond are donated by the same atom

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16
Q

what are the 4 intramolecular forces?

A
  • London dispersion
  • dipole-dipole
  • hydrogen bond
  • electrostatic forces
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17
Q

what bonds have London dispersion forces?

A

diatomic or non-polar covalent

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18
Q

what bonds have dipole-dipole forces?

A

polar covalent bonds with partial charge change

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19
Q

what elements create hydrogen bond forces when combined with hydrogen?

A

oxygen, nitrogen or fluorine

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20
Q

what type of force is hydrogen bonds?

A

special dipole-dipole

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21
Q

what bonds have electrostatic forces?

A

ionic bonds

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22
Q

how do you find the bond type?

A

change in electronegativity

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23
Q

how do you find the type of intramolecular forces?

A

looking at the type of bond

24
Q

non polar or polar molecule: linear diatomic?

25
non polar or polar molecule: linear - two different elements?
polar
26
non polar or polar molecule: linear - X-A-X format?
non-polar
27
non polar or polar molecule: bent/angular with unshared pairs?
polar
28
non polar or polar molecule: trigonal planar?
non-polar
29
non polar or polar molecule: trigonal pyramidal?
polar
30
non polar or polar molecule: tetrahedral?
non-polar
31
how to tell if vsepr is non-polar or polar?
if E is not 0 it is polar
32
ionic bond melting/boiling point
high
33
metallic atom melting/boiling point
high
34
non-polar covalent melting/boiling point
low
35
polar molecules melting/boiling point
low
36
covalent networks boiling/melting point
very high
37
ionic electrical conductivity
good when dissolved in water or melted
38
metallic electrical conductivity
great in solid and liquid
39
non-polar covalent electrical conductivity
poor
40
polar covalent molecule electrical conductivity
poor
41
covalent network electrical conductivity
poor - graphite is an exception
42
ionic thermal conductivity
poor
43
Metallic Thermal Conductivity
good
44
non-polar Thermal Conductivity
poor
45
polar Thermal Conductivity
poor
46
covalent networks thermal conductivity
poor
47
ionic state at room temperature
solid
48
metallic state at room temperature
solid to liquid
49
non-polar state at room temperature
solid, liquid or gas
50
polar state at room temperature
solid, liquid or gas
51
covalent networks state at room temperature
solid
52
intramolecular forces from greatest to weakest
electrostatic, hydrogen bonding, dipole-dipole, London dispersion
53
why do different compounds have different boiling points?
it depends on the intramolecular forces
54
how do intramolecular forces affect boiling points?
the stronger the force, the higher the boiling point
55
Why are ionic compounds brittle?
Ionic compounds are brittle due to the strong bond between the positive and negative ions that make up the molecules. Applying pressure shifts the alignment of the ions and results in brittleness.