bonds Flashcards
Covalent bonds are formed by…
the overlapping of atomic orbitals
The Sigma (σ) Bond
head-on positive (same phase) overlap of atomic orbitals along the internuclear axis.
____ are the strongest covalent bonds
Sigma bonds
s-s Overlapping (Sigma bonds)
- one ‘s’ orbital from each participating atom undergoes head-on overlapping along the internuclear axis.
- An s orbital must be half-filled before it overlaps with another.
s-p Overlapping (sigma bond)
one half filed s orbital overlaps with one half-filled p orbitals along the internuclear axis, forming a covalent bond.
p-p overlapping (sigma bond)
one half-filled p orbital from each participating atom undergoes head-on overlapping along the internuclear axis
The Pi (π) Bond
formed by the sidewise positive (same phase) overlap of atomic orbitals along a direction perpendicular to the internuclear axis.
How Many Pi/sigma Bonds Exist in Double Bonds?
one pi bonds and one sigma bond
What is the Number of Sigma and Pi bonds in a Benzene Molecule?
12 sigma bonds and 3 pi bonds
How Many Pi/sigma Bonds Exist in Triple Bonds?
one sigma bond and two pi bonds