Chemical and biogeochemical effects Flashcards

1
Q

How does the ability of the oceans to absorb CO2 change as atmospheric CO2 changes?

A

The ability of sea water to absorb CO2 drops as atmospheric CO2 increases

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2
Q

How do phytoplankton respond to iron availability?

A

If there is more dust present, there is more iron available … this encourages phytoplankton growth

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3
Q

What chemical processes do we need to consider in our models?

A
  • Ocean chemistry
  • Role of ozone
  • Atmospheric chemistry
  • Methane lifetime
  • Volatile Organic Compounds (VOCs)
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4
Q

What is the average pH of the oceans?

A

pH 8

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5
Q

How does the ocean act as a biological pump?

A
  • Phytoplankton absorb CO2
  • Zooplankton consume phytoplankton
  • Respiration returns CO2 to the atmosphere
  • Some organic matter sinks to the deep ocean … net uptake of CO2
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6
Q

Where is CO2 recycled in the ocean?

A

In the upper 1 km

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7
Q

What % of organic matter sinks to the deep ocean?

A

5-10%

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8
Q

What is phytoplankton growth limited by?

A
  • Light

- Nutrients (nitrogen, phosphorous, iron)

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9
Q

In what regions is iron a major limiting nutrient?

A
  • Equitorial pacific

- Southern Ocean

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10
Q

How is iron delivered to the ocean?

A

Through dust

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11
Q

Where in the ocean do your find nutrient ‘deserts’?

A

The centre of gyres

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12
Q

Who proposed the iron hypothesis?

A

John Martin

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13
Q

What is the iron hypothesis?

A
  • Fertilise low-chlorophlull zones
  • Create algal blooms
  • Boost primary productivity
  • Drive down CO2
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14
Q

How many studies on iron fertilisation experience have shown a CO2 draw down?

A

Only one of over 12 studies … (Boyd, 2000: showed a doubling of biomass and a CO2 draw down)

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15
Q

When were commercial iron fertilisation experiments banned?

A

2013

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16
Q

Which convention prevents iron fertilisation experiments?

A

The UN convention on biological diversity

17
Q

How much dust was dumped into the oceans after the Pinatubo eruption?

A

40,000 tonnes

18
Q

How could the relationship between iron availability and climate cause a positive feedback loop?

A

-warmer, wetter climate … less dust … less iron deposition … fewer nutrients … fewer phytoplankton … less oceanic CO2 absorption

19
Q

How could the relationship between iron availability and climate cause a negative feedback loop?

A

-arid regions get drier … more dust … more iron deposition … more nutrients … more phytoplankton … more oceanic CO2 absorption

20
Q

What is DMS?

A

Dimethyl Sulphide … emitted by phytoplankton as a natural byproduct of metabolism

21
Q

What is one hypothesis for why DMS is emitted?

A

To protect phytoplankton from UV radiation

22
Q

What does DMS do?

A
  • gives the sea water its smell

- forms natural aerosol

23
Q

What is the chemical formula for DMS?

A

(CH3)2S

24
Q

What happens to DMS in the atmosphere?

A

Oxidised and condensed into aerosols

25
Q

What is the CLAW hypothesis?

A

A negative climate feedback loop

  • ocean warms
  • enhanced phytoplankton growth
  • enhanced DMS production
  • More aerosol produced
  • More cloud condensation nuclei
  • Ehanced cloud area
  • Enhanced albedo … reflecting sunlight
26
Q

Who proposed the CLAW hypothesis?

A

C-Charlson
L-Lovelock
A-Andreae
W-Warren

27
Q

When was the CLAW hypothesis first proposed?

A

1897

28
Q

What is the controversy surrounding the CLAW hypothesis?

A

Lovelock (one who originally proposed the hypothesis) contracted this in The Revenge of Gaia … could it be a positive loop instead? … increased stratification … reduced upwelling … less DMS production …

29
Q

How much is the stratosphere cooling?

A

0.5ºC a decade

30
Q

What is chemistry of the ozone dependent on?

A

Temperature

31
Q

What is occurring in polar regions due to reducing stratospheric temperature?

A

More polar stratospheric clouds are generated … these provide the surface on which chemical reactions occur that creates the ozone hole

32
Q

What is the atmospheric lifetime of methane and what does this mean?

A

12 years … meaning half is removed in 12 years

33
Q

Why does methane emission rate affect its lifetime?

A

More emissions reduces OH concentration, increasing methane lifetime

34
Q

What is the OH radical important for?

A

Important for chemical reactions that remove methane from the atmosphere … it is described as the ‘atmospheric detergent’

35
Q

What is produced in the oxidation of methane?

A

Stratospheric water vapour

36
Q

What is stratospheric water vapour important for?

A

The formation of stratospheric clouds which accelerate ozone depletion

37
Q

Why do plants produce VOCs?

A

Unsure of this … requires a lot of energy from the plant so there must be a reason for this … communication? protect against predation?

38
Q

How does a warming planet affect VOC emissions?

A

Warmer temperatures cause more VOCs to be emitted … due to increased metabolism