Chemical analysis Flashcards

1
Q

What is chemical analysis?

A

The process of establishing what chemicals are present in a substance

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2
Q

In everyday language, what is a “pure” substance

A

A substance that has had nothing added to it and is in its “natural state”

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3
Q

In chemistry, what is a “pure” substance?

A

A substance made of a single element or compound

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4
Q

How can pure substances be distinguished from impure ones?

A

By their boiling and melting points

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5
Q

Describe the melting and boiling points of pure substances

A

One very specific temperature

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6
Q

Describe the melting and boiling point of impure substances

A

They change state at a range of temperatures

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7
Q

What is a formulation?

A

A complex mixture designed as a useful product

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8
Q

Give three examples of formulations

A

Fuels, cleaning agents, paints, medicines, alloys, fertilisers and foods

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9
Q

What is chromatography?

A

A process to separate the constituents of a mixture

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10
Q

In paper chromatography, what is the stationary phase and what is the mobile phase?

A

Paper is stationary, solvent (usually water or ethanol) is the mobile

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11
Q

How can chromatography show the difference between pure and impure substances?

A

Pure ones will not separate into a number of spots

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12
Q

How is the Rf value calculated?

A

Distance moved by spot/distance moved by solvent

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13
Q

What does a substance’s Rf value depend on?

A

How soluble it is in the solvent

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14
Q

In chromatography, why must the substance be placed on a pencil line?

A

Pencil will not dissolve in the solvent (insoluble)

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15
Q

In chromatography, why must the solvent height be lower than the pencil line?

A

So that the substances do not dissolve into the solvent off the paper

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16
Q

How can hydrogen be tested for?

A

Makes a squeaky pop when a plit is placed in it

17
Q

How can oxygen be tested for?

A

Relights a glowing splint

18
Q

How can carbon dioxide be tested for?

A

Bubble through limewater; turns it cloudy/milky

19
Q

How can chlorine be tested for?

A

Bleaches damp litmus paper white

20
Q

What is a flame test?

A

A test to identify metal ions (cations)

21
Q

What is the colour of the flame produced from compounds containing;’ lithium, sodium, potassium, calcium, copper

A

Crimson, yellow, lilac, orange-red, green

22
Q

Which solutions produce white precipitate on addition of sodium hydroxide?

A

Solutions containing aluminium, magnesium, and calcium ions

23
Q

How can a solution of aluminium ions be distinguished from calcium and magnesium ones?

A

It’s precipitate will dissolve in excess sodium hydroxide

24
Q

What is the colour of the precipitate formed from the addition of sodium hydroxide to a solution containing copper (II) ions?

25
What is the colour of the precipitate formed from the addition of sodium hydroxide to a solution containing iron (II) ions?
Green
26
What is the colour of the precipitate formed from the addition of sodium hydroxide to a solution containing iron (III) ions?
Brown
27
What is the test for carbonates?
Add an acid to generate carbon dioxide gas. Bubble through limewater
28
What is the test for halides?
Add silver nitrate and nitric acid to generate a solid silver halide precipitate
29
What are the colours of the silver halides?
Silver chloride; white, Silver bromide; cream, Silver iodide; yellow
30
What is the test for sulfate ions
Add Barium chloride and hydrochloric acid - forms white precipitate
31
What is an instrumental method?
Use of scientific technology to perform chemical analysis
32
# Halide test Positive test for chloride
White ppt of silver chloride
33
# Halide test Positive test for bromide
Cream ppt of silver bromide
34
# Halide test Positive test for iodine
Yellow ppt of silver iodide
35
Instrumental analysis example
Flame emission spectroscopy