Chemical Analysis Flashcards

1
Q

What is a pure substance?

A

A substance containing a single element or compound (that is not mixed with another substance)

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2
Q

What is an impure substance?

A

A substance containing more than one type of element or compound in a mixture.

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3
Q

How do you calculate the Rf value?

A

Distance moved by substance / distanced moved by solvent

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4
Q

What numbers will the Rf value always be between?

A

0 and 1

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5
Q

In chromatography, what is shown by how far the substance moves up the paper?

A

Higher up = more soluble

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6
Q

In chromatography, what does it mean if a substance produces only one spot?

A

It is pure

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7
Q

In chromatography, why must the line be drawn in pencil?

A

Pen would dissolve and travel up the paper

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8
Q

What is the test for hydrogen?

A

Hold a lit splint near gas.
Positive = squeaky pop sound

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9
Q

What is the test for oxygen?

A

Hold glowing splint near gas.
Positive = splint relights

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10
Q

What is the test for carbon dioxide?

A

Bubble gas through limewater.
Positive = limewater turns cloudy

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11
Q

What is the test for chlorine?

A

Hold piece of damp litmus paper near gas.
Positive = litmus paper bleached white

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12
Q

How do you test for aluminium ions?

A

Slow addition of excess sodium hydroxide solution
Positive = white precipitate that eventually dissolves.

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13
Q

How do you test for calcium ions?

A

Addition of excess sodium hydroxide solution
Positive = white precipitate that does not dissolve.

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14
Q

How do you test for magnesium ions?

A

Addition of excess sodium hydroxide solution
Positive = white precipitate that does not dissolve.

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15
Q

How do you test for copper (II) ions?

A

Add sodium hydroxide solution
Positive = blue precipitate

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16
Q

How do you test for iron (II) ions?

A

Add sodium hydroxide solution
Positive = green precipitate

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17
Q

How do you test for iron (III) ions?

A

Add sodium hydroxide solution
Positive = brown precipitate

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18
Q

How do you test for carbonate anions?

A

Add dilute acid
Positive = CO2 gas formed

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19
Q

How do you test for chloride anions?

A

Add silver nitrate solution in presence of nitric acid
Positive = white precipitate formed

20
Q

How do you test for bromide anions?

A

Add silver nitrate solution in presence of nitric acid
Positive = cream precipitate formed

21
Q

How do you test for iodide anions?

A

Add silver nitrate solution in presence of nitric acid
Positive = yellow precipitate formed

22
Q

How do you test for sulfate anions?

A

Add barium chloride solution in presence of hydrochloric acid
Positive = white precipitate formed

23
Q

Flame tests: what is the positive result for lithium?

24
Q

Flame tests: what is the positive result for sodium?

25
Flame tests: what is the positive result for potassium?
Lilac
26
Flame tests: what is the positive result for calcium?
Orange-red
27
Flame tests: what is the positive result for copper?
Green
28
What is instrumental analysis?
Using complex scientific equipment to identify substances.
29
What are 3 advantages of instrumental analysis?
Quick, accurate, sensitive
30
What information does flame emission spectroscopy produce?
The wavelength of light given off by metal in a flame To identity of the metal and its concentration
31
What group of the Periodic Table are the halogens found in?
Group 7
32
What are ions of Group 7 elements known as?
Halide ions
33
What is added to halide ions when tested for?
Nitric acid, then silver nitrate
34
What precipitate is formed by a chloride ion? (in nitric acid + silver nitrate solution)
White
35
What precipitate is formed by a bromide ion? (in nitric acid + silver nitrate solution)
Cream
36
What precipitate is formed by an iodide ion? (in nitric acid + silver nitrate solution)
Yellow
37
What are flame tests used to test for?
Alkali metals
38
What group on the Periodic Table is the alkali metals?
Group 1
39
What colour does a flame turn when lithium ions are present?
Crimson
40
What colour does a flame turn when sodium ions are present?
Yellow-orange
41
What colour does a flame turn when potassium ions are present?
Lilac
42
What colour does a flame turn when calcium ions are present?
Brick red
43
What colour does a flame turn when barium ions are present?
Apple green
44
What is the mobile phase in chromatography?
The solvent that moves through the paper, carrying different substances with it
45
What is the stationary phase in chromatography?
It is contained on the paper and does not move through it (e.g: chromatography paper)