Chem2 Flashcards

1
Q

4 major components of dry air

A

nitrogen, oxygen, argon, carbon dioxide

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2
Q

nitrogen fixation done by

A

lightning. N2+O2–>2NO. then reacts further with oxygen and water to form nitrous and nitric acids

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3
Q

thermosphere

A

ionosphere. warms with altiutude because of ions from sun. auroras

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4
Q

warming in stratosphere

A

uv radiation from sun triggers exothermic reactions. more UV is closer to sun so increaseds with altitude.

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5
Q

low pressure at?

A

high altitudes

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6
Q

how do barometers work

A

mercury pumped easier at high pressure. cant pump in alps (galileo and torricelli)

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7
Q

Why does the egg go into the bottle?

A

Pressure outside was greater than pressure inside. outside greater due to production of more gas

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8
Q

thermosphere charged particles

A

e+O

p+N2 charges those and gives off light as they go back to regular forms (down in energy level).

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9
Q

space shuttle glow

A

O+NO—> NO2* excited, goes back to regular form, gives off orange tail

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10
Q

chapman cycle

A
creation and destruction of ozone. no net change in concentration
O2+UV-->2O
O2+O-->O3
O3+UV---> O2+O
O3+O-->2O2
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11
Q

ozone thickness

A

only 3mm thick. stretches about 30 miles though.starts at 20-30km. not pure ozone. Just in a high concentration

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12
Q

UV A

A

lest energy, longest wavelength, least damaging, greatest amount reaching earth

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13
Q

UV B

A

more damaging, most absorbed by ozone in atmosphere. 200-300nm. 97-99 blocked%

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14
Q

UV C

A

most energy, shortest wavelength, most damaging. totally absorbed by oxygen/ozone. No makes it to the service

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15
Q

UV radiation biological effect

A

damages DNA. UVB. increase in melanoma.

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16
Q

variations in ozone levels

A

vary every 12 years due to solar intensity/sunspot activity, seasonal variation, 10% decrease over past 3 decades

17
Q

ozone depletion where?

A

Antarctica

18
Q

what can destroy the ozone

A

additional trace gases

19
Q

natural trace gases

A

hydroxyl radicals. unsatble and reactive with an unpaired electron. destorys in upper stratosphere. nitric oxide (NO) from lightning

20
Q

anthropogenic (man-made) trace gases

A

from combustion- NO, jet engines. Chlorine radical from CFCS

21
Q

CFCS

A

chlorofluorocarbons. refrigerants replacing ammonia and sulfur dioxide (corrosive and toxic)

22
Q

CFC properties

A

nontoxic, nonflammable and unreactive in the troposphere (long half life). reactive in stratosphere.

23
Q

Cl radical

A

catalyst, consumed and regernated as it destroys ozone. becomes clo (measure concentration of this and 03 over ozone)