chem final Flashcards
carbs are made of
C,H, and O
energy source, ends in “ose”
monosaccharides
simplest, cannot be split (glucose)
disacccharides
2 monosaccharides joined, split by hydrosis
formed by dehydration
maltose, lactose, sucrose
polysaccharides
contains many monosaccharides, can be split by hydrolysis (sucrose +h20)
amylose, amylopectin, cellulose, glycogen
formed by glucose rings
aldehyde
on the end, carbon 1
carbonyl
C=O
ketone
between two carbons
structural isomer
same molecular formula, dif arrangment
stereoisomer
double bond, look at H, seperate C atoms
chiral
completely matched, non-superimposable images
e.g. shoes
can be sorted into left and right
achiral
identical mirror images
e.g. socks
cannot be sorted
chirality center
C atom in tetrahedral
achiral center
structures are not aligned
vertical lines
bonds project backwards
horizontal lines
bonds project forward
glyceraldehyde
1 chiral C
important monosaccharides
glucose, galactose, fructose
Haworth Structures of Monosaccharides
open chains, more stable form pentoses and hexoses
closed ring structure
alpha isomer
OH is below ring
beta isomer
OH is above ring
oxidation of monosaccharides
aldehyde group forms a carboxylic acid
increases # of C-O bonds
reduction of monosaccharides
decrease C-O bonds
produces alcohol
used in many sweeteners for “sugar free”
hyperglycimia
high levels of glucose, turns urine red
glycosidic bond
connects to monosaccharides
in Splenda, some of the hydroxyl groups are replaced with
Cl atoms
starch
20% amylose, 80% amylopectin
amylose
straight chain of glucose
⍺-1–>4
amylopectin
branched chain of glucose
⍺-1–>6
glycogen
maintains blood glucose levels, branched
stored in the liver and muscles
cellulose
all glucose units, straight chain, cannot be digested, insoluble in water
wood, cotton
carboxylic acids
weak acid, sour taste, produce H30+ in water, neutralize bases
IUPAC Names of Carboxylic Acids
replace “e” of alkane name with “oic acid”
Properties of Carboxylic Acids
2 polar groups (hydroxyl & carbonyl)
dissociation in h20
most acidic
weak acids
esters
carboxylic acid reacts with an alcohol
esterfication
presence of heat and acid catalyst (excess alcohol)
carboxylate ion shows a name change from
ic acid to ate ion
small esters
volatile (evaporate easily)
amines
contain nitrogen, derivatives of ammonia (NH3)
alkyl
straight chain carbon
aromatic amines
analine
alkyl groups attached to nitrogen (of analine) are named with the prefix
N- followed by the akyl name
on aromatic ring
Solubility of Amines in Water
Amines have polar N–H bonds, they form hydrogen bonds with water
hydrogen bonding: N,O,F