chem chp 2 solution Flashcards
what is a solution?
> homogenous mixture of 2 or more subs
true solution consists of a solvent and and a solute
saturated solution
> is a solution that contains max amt of solute in given amt of solvent at given temp.
after reaching the point of eqm. dissolution stops and crystallization starts which leads to orecipitate occurence
henrys law
the solubility of gas in liquid is directly proportional to the pressure of gas over the solution
s=khp
unit of KH
mol L^-1 bar^-1
raoults law
partial v.p of any volatile component of a solution = vp of pure component multiplied by its mole fraction in the solution
positive deviation
solutions in which solute-solvent intermolecular attractions are weaker than those between solute-solute molecules and solvent-solvent molecules
negative deviation
solutions in which solute-solvent intermolecular attractions are higher than those between solute-solute molecules and solvent-solvent molecules
eg of non ideal solutions
ethanol+acetone
carbon disulphide+acetone
phenol+aniline
chlroform+acetone
colligative props
physical prop of sol. that depends on the no.of the solute particles in sol and not on their nature