chem chemical bonds Flashcards

1
Q

chemical bonds

A

atoms come together in small or large bonds forming stable associations
-metallic
-covalent
-ionic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

why do chemical bonds occur§?

A

as a result of changes in the distribution of e

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

ionic bonds

A

-ions are in a lattice structure
-more flexible when elements come from diff ends

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

positive ions

A

cations
lose e

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

negative ions

A

anions
gain e

ending in -ide

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

nuclear charge

A

=atomic numb

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

ionic exceptions

A

Fe 2 3
Pb 2 4
Sn 2 4
Ag 1
Cu 1 2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

what is the effective n c and the n c of Li?

A

+1 and 3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

diagram for formation of cations and anions

A

the circles that represent the energy levels with electron pairs

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

equation for formation of cations and anions

A

Al = Al3+ + 3e cation anion
N+ 3e = N3-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

ionic bonding

A

instead of ionic bond
-one atom donates e one accepts

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

NaClO

A

ionic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

in which cases is it harder to add e?

A

increasing neg charge due to increased e e repulsion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

ultimate goal

A

stable electron conf
metals- noble gas proceeding
non metals- noble gas succeeding

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

polyatomic ions

A

NO3-
SO4 2-
PO4 3-
OH-
HCO3 -
CO3 2-
NH4 +

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

lattice structure

A

-neutral charge
-electrostatic force
fixed arrangement

17
Q

lattice enthalpy

A

energy needed to break an ionic bond, separate ions, it is endothermic so positive NaCl Na Cl
-bigger ions smaller enthalpy
-bigger ion charge bigger enthapy

18
Q

prop-high melting and boiling points

A

-because a lot of E in necessary to separate the ions in the lattice
-higher when ionic charge is greater (like lattice enthalpy)

19
Q

prop-volatility

A

non volatile because of strong electrostatic attractions

20
Q

prop-solubility

A

-in water
-not in non polar
-the attraction of the surface crystal ions t the water molecule pulls the ions away from lattice positions

21
Q

hydration energy

A

energy given out when the ions become hydrated

22
Q

prop-conductivity

A

-high electrical conductivity
-only in aq or l states
-only when molten because then the ions are free to move and therefore conduct

23
Q

prop-brittle

A

it breaks with force

24
Q

% ionic character

A

electronegativity diff : 3.2
-zero= non polar covalent
-zero to 1.8= polar covalent
-1.8 < = ionic

25
Q

Delta xp

A

electroneg. diff, CsF is 3.2, 100% ioc

26
Q

actual tests to determine ionic comp

A

-melting point
-conductivity
-solubility

27
Q

to oxidize

A

it means to cause a reaction in which e are lost to another species

28
Q

covalent bond

A

electrostatic attraction between a shared pair of e and the nuclei of the atoms making up the bond

29
Q

formation of covalent bond

A

-draw=two circles connected with shared electrons
-when two non metals react they are seeking to gain e to achieve a stable e conf of a noble gas, so they share electrons