chem bonding and structure Flashcards

1
Q

structure of ionic compound

A

giant ionic lattice structure

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2
Q

structure of molecules

A

simple molecular structure

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3
Q

structure of macromolecules

A

giant molecular structure

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4
Q

structure of metals

A

giant metallic structure

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5
Q

bonding within ionic compound

A

strong electrostatic forces of attraction between cations and anions

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6
Q

bonding within molecules

A

1) strong covalent bonds between atoms
2) weak intermolecular forces of attraction between molecules (VDW)

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7
Q

bonding within macromolecules

A

strong covalent bonds between atoms

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8
Q

bonding within metals

A

strong electrostatic forces of attraction between metal cations and delocalised electrons

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9
Q

electrical conductivity of ionic compounds

A

good in molten or aq states,

in solid states, strong EFOA between oppositely charged ions hold the ions in fixed position. The ions can only vibrate about their fixed position and are not able to move about freely. hence there are no mobile charge carriers to conduct electricity.

in molten or aq states, strong EFOA between oppositely charged ions are overcome. these ions are free to move around. hence electricity can be conducted by these mobile ions

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10
Q

electrical conductivity of molecules

A

poor

they are neutral molecules and do not contain mobile ions or delocalised electrons to act as charge carriers to conduct electricity

except for those that dissociate to form ions (basically acids)

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11
Q

electrictal conductivity of macromolecules

A

does not conduct electricity except graphite

all the outer shell electrons of carbon atoms are used to form covalent bonds hence there are no delocalised electrons to conduct electricity

but graphite conducts electricity, 1 valence electrons per carbon atom is not used to form covalent bonds. these electrons are delocalised d along the same plane and allow graphite to conduct electricity along the laters

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12
Q

mp/ bc of ionic compound

A

high. ionic compounds have giant lattic structure and strong efoa between oppositely charged ions. larger amount of energy is needed to overcome strong efoa between oppositely charged ions

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13
Q

mp/bp of molecules

A

low, because between molecules, there are only weak intermolecular molecules holding them tgt, only a small amt of energy is needed to overcome this weak intermolecular forces of attraction between molecules.

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14
Q

mp / bp of macromolecule

A

very high (greater than 3000) because large amts of energy is needed to overcome the numerous strong covalent bonds between atoms inn giant structure

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15
Q

mp / bp of metals

A

high. metals have a giant metallic structure with strong efoa between cations and sea of delocalised electrons. a large amount of energy is required to overcome these strong efoa between cations and sea of delocalised electrons

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16
Q

physical state of ionic compound at rtp

A

solid

17
Q

physical state of molecules at rtp

A

liquid / gas

18
Q

physical state of macromolecules at rtp

A

solid

19
Q

physical state of metals at rtp

A

solid, except for mercury

20
Q

how are metallic bonds formed

A

metals have low ionisation energies, and lose electrons easily to become ions. their valence electrons form a sea of delocalised electrons. hence, efoa between sea of delocalised electrons and metal cations are formed.

21
Q

how are ionic bonds formed

A

electrons are transferred from metal atoms to non metal atoms, forming cations and anions with stable electronic configuration of noble gas. they are held together in giant ionic lattice by strong efoa because of oppositely charged ions