chem bonding and structure Flashcards
structure of ionic compound
giant ionic lattice structure
structure of molecules
simple molecular structure
structure of macromolecules
giant molecular structure
structure of metals
giant metallic structure
bonding within ionic compound
strong electrostatic forces of attraction between cations and anions
bonding within molecules
1) strong covalent bonds between atoms
2) weak intermolecular forces of attraction between molecules (VDW)
bonding within macromolecules
strong covalent bonds between atoms
bonding within metals
strong electrostatic forces of attraction between metal cations and delocalised electrons
electrical conductivity of ionic compounds
good in molten or aq states,
in solid states, strong EFOA between oppositely charged ions hold the ions in fixed position. The ions can only vibrate about their fixed position and are not able to move about freely. hence there are no mobile charge carriers to conduct electricity.
in molten or aq states, strong EFOA between oppositely charged ions are overcome. these ions are free to move around. hence electricity can be conducted by these mobile ions
electrical conductivity of molecules
poor
they are neutral molecules and do not contain mobile ions or delocalised electrons to act as charge carriers to conduct electricity
except for those that dissociate to form ions (basically acids)
electrictal conductivity of macromolecules
does not conduct electricity except graphite
all the outer shell electrons of carbon atoms are used to form covalent bonds hence there are no delocalised electrons to conduct electricity
but graphite conducts electricity, 1 valence electrons per carbon atom is not used to form covalent bonds. these electrons are delocalised d along the same plane and allow graphite to conduct electricity along the laters
mp/ bc of ionic compound
high. ionic compounds have giant lattic structure and strong efoa between oppositely charged ions. larger amount of energy is needed to overcome strong efoa between oppositely charged ions
mp/bp of molecules
low, because between molecules, there are only weak intermolecular molecules holding them tgt, only a small amt of energy is needed to overcome this weak intermolecular forces of attraction between molecules.
mp / bp of macromolecule
very high (greater than 3000) because large amts of energy is needed to overcome the numerous strong covalent bonds between atoms inn giant structure
mp / bp of metals
high. metals have a giant metallic structure with strong efoa between cations and sea of delocalised electrons. a large amount of energy is required to overcome these strong efoa between cations and sea of delocalised electrons