Chem 40 Flashcards

1
Q

Carbohydrates

A
  • Hydrates of carbon
  • Main function is to provide
    energy
  • most abundant biomolecules on Earth
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2
Q

________ converts more than 100 billion metric tons of CO2 and
H2O into cellulose and other plant products

A

Photosynthesis

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3
Q

a multistep process that forms carbon
dioxide, water, and a great deal of energy

A

oxidation of glucose

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4
Q

Functions of Carbohydrates

A
  • Storehouse of chemical energy.
  • Supportive structural components of plants and some animals.
  • Essential components of the genetic material
  • Ligands and receptors in cellular communication
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5
Q

Classes of Carbohydrates

A
  • monosaccharides
  • oligosacchraides
  • Polysaccharides
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6
Q

Monosaccharides

A

simple sugars, consist of a single polyhydroxy aldehyde or ketone unit. The most abundant monosaccharide in nature is the six-carbon sugar D-glucose

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7
Q

Oligosaccharides

A
  • consist of short chains of monosaccharide units joined by characteristic linkages called glycosidic bonds
  • Disaccharides
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8
Q

Polysaccharides

A
  • sugar polymers containing more than 20 or so monosaccharide units, and some have hundreds or thousands of units
  • Example: Cellulose
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9
Q

have three to seven carbon atoms in a chain, with a carbonyl group at either the terminal carbon (C1) or the carbon adjacent to it (C2).

A

monosaccharides

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10
Q

Monosaccharides are usually drawn _______ , with the carbonyl group at
the _____

A

vertically; top

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11
Q

polar compounds with high melting points

A

monosaccharides

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12
Q

What makes monosaccharides water soluble?

A

presence of so many polar functional groups capable of hydrogen
bonding

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13
Q

Two families of monosaccharides

A

aldoses
ketoses

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14
Q

[aldose or ketose] If the carbonyl group is at an end of the carbon chain of the monosaccharide

A

aldose

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15
Q

[aldose or ketose] if the carbonyl group is at any other position of the
monosaccharide

A

ketose

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16
Q

simplest aldehyde

A

glyceraldehyde

17
Q

simplest ketone

A

dihydroxyacetone

18
Q

monosaccharide with 3Cs, 4C’s, 5Cs, 6Cs

A

triose (3)
tetrose (4)
pentose (5)
hexose (6)

19
Q

[Stereoisomerism] Aldoses & ketoses
(except dihydroxyacetone) are

A

OPTICALLY ACTIVE

20
Q

[T or F] d and l refers to the direction in which plane polarized light is rotated

A

True

21
Q

[clockwise or counterclockwise] - D

A

clockwise

22
Q

[clockwise or counterclockwise] - L

A

counterclockwise

23
Q

Stereoisomers

A

isomers that differ in spatial arrangement of atoms, rather
than order of atomic connectivity

24
Q

Anomeric carbon

A

carbonyl carbon (C=O)

25
Q

Penultimate carbon

A

2nd to the last carbon

26
Q

number of possible stereoisomers of a monosaccharide _____ _____ with the number of ______ ______ present

A

increases exponentially; stereogenic centers

27
Q
A