Chem Flashcards

1
Q

Hund’s Rule

A

Orbital’s are singularly occupied before they are doubly occupied

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2
Q

Pauli’s Exclusion Principle

A

No electrons can occupy the same Quantum state

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3
Q

Aufbau Principle

A

Electrons occupy lower energy levels before they occupy higher energy levels

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4
Q

Overall energy change of a system

A

H(products)-H(reactants)

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5
Q

bond energy calculations

A

H(reactants)-H(products)

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6
Q

Q=mcdeltaT

A

Measurement for heat capacity
m- mass in grams
c- specific heat capacity in kj per gram (decimal)
Delta T - temperature in whatever unit

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7
Q

Dispersion forces are greater for…

A

heavier or larger atoms

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8
Q

Dipole - dipole forces are greater for…

A

a greater electronegativity difference

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9
Q

1 gram to milligrams

A

1000 milligrams to a gram

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10
Q

Yield….

A

the amount of product produced from a reaction

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11
Q

% Yield =

A

ex. yield/ theoretical yield * 100

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12
Q

Acid + reactive metal –>

A

salt + hydrogen

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13
Q

Acid + metal hydroxide –>

A

salt + water

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14
Q

Acid + metal carbonate –>

A

salt + water + carbon dioxide

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15
Q

Vapour pressure and Intermolecular forces relationship

A

substances with stronger intermolecular forces have lower vapour pressure, as the molecules have less kinetic energy as they are connected more tightly than substances with weaker intermolecular forces.
e.g non-polar substances have greater vapour pressure than polar ones, because hydrogen bonding is stronger than dispersion forces

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16
Q

Trends in solubility

A

bromide, chloride, idiode, nitrate and sulfate are mostly soluble
carbonate, hydroxide, oxide and phosphate are mostly insoluble
NITRATE IS ALWAYS SOLUBLE
Silver is USUALLY insoluble, except for nitrate and sulfate (p)

17
Q

Spectator ions

A

are the ones that don’t precipitate

18
Q

m/v equals

A

mass/volume

19
Q

All sections in a reaction must

A

have the same rate

20
Q

Acids dissociate to produce
Bases dissociate to produce

A

H+

OH-

21
Q

All ionic compounds are

A

polar and therefore all have high boiling points and low vapour pressure

22
Q

Nanomaterials are

A

from 1-100nm long and often show different properties than larger samples of the same material
they have specialised carbon structures such as nanotubes, graphene and fullerene

23
Q

Flame colours indicate the metal used

A

as flame colours are due to excited ions, jumping an orbital, emitting electromagnetic radiation