chem Flashcards

1
Q

n=4

l,ml, total orbitals,electrons

A

l=0,1,2,3
ml=0,-+1,-+2,-+3,
16 (4 squared)
32 electrons

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2
Q

n=5

l,ml, total orbitals,electrons

A

l=0,1,2,3,4
ml=0,-+1,-+2,-+3,+-4
25 (5 squared) orbitals
50 electrons

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3
Q

How does the radial probability plot and electron probability distribution look like

A

Goes up (1/4) and back down

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4
Q

how does the p orbitals look like?

A

two lobes and nucleus is on a plane that divides the lobes

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5
Q

how does d orbitals look like?

A

four lobes and one of them (dz2) has two and a ring

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6
Q

What are the 3 known electron configuaration anomolies

A

Cr, Cu, Mo
Chromium, Copper, Molybednum

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7
Q

diamagnetism

A

all of electrons are paired

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8
Q

paramagnetism

A

atoms with unpaired electrons

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9
Q

What 2 things make an atom bigger

NOT THE TREND, THE REASON

A

decreasing ZEFF, increasing electron electron repulsion making e- cloud bigger

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10
Q

What groups are the anomolies of IE in?

A

Group 3, 6

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11
Q

What groups is electron affinity +

and why

A

2,5 (just nitrogen), 8

energy must be added to add an additional electron

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12
Q

electronegativity of C,N,O,F (2nd period)

A

C: 2.5
N:3.0
O:3.5
F:4.0

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13
Q

Electronegativity of P, S, Cl (3rd period)

A

P: 2.2
S:2.6
Cl:3.0

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14
Q

Electronegativity of Br, I (4th and 5th halogens)

A

Br: 2.8
I:2.5

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15
Q

Ionic Compounds

  1. physical state
  2. melting and boiling point
  3. solubility in water
  4. Electrical Conductivity
A
  1. Exist as solids at room temp
  2. high melting and boiling
  3. dissolve in water
  4. do not conduct electricity in wolid state, does conduct in molten state
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16
Q

covalen compounds

  1. physical state
  2. melting and boiling point
  3. solubility in water
  4. Electrical Conductivity
A
  1. exist as gases, liquids, solids at room temp,
  2. low melting and boiling,
  3. do not dissolve in water,
  4. do not conduct electricity
17
Q

metallic

  1. physical state
  2. melting and boiling point
  3. solubility in water
  4. Electrical Conductivity
A
  1. exist as solids at room temp
  2. high melting and boiling temp
  3. do not dissolve in water
  4. good conductors of electricity in solid/molten
18
Q

Zinc charge

19
Q

Ammonium charge

20
Q

nitrate

21
Q

sulfate

22
Q

phosphate!

23
Q

Carbonate

24
Q

Perchlorate (4)

25
Acetate C2H3O2
C2H3O2-
26
Hypovalent molecules
Boron, beryllium, alluminum
27
What is the most repulsive
Lone pair lone pair repulsions
28
What is the least repulsive
Bond pair Bond pair repulsions
29
Trigonal planar makes what? SN?
SN=3, bent
30
tetrahedral
SN=4 trigonal pyramidal, bemt
31
trigonal byprimidal
SN=5 See Saw, T shape, Linear
32
Octahedral
SN=6 Square pyramidal, square planar 90 degrees
33
Polar bonds have
Dipole moments
34
Sigma bond
head to head overlap ON internuclear axis
35
Pi bonds
Side to side interlaps perpendicular to internuclear axis