chem Flashcards

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1
Q

n=4

l,ml, total orbitals,electrons

A

l=0,1,2,3
ml=0,-+1,-+2,-+3,
16 (4 squared)
32 electrons

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2
Q

n=5

l,ml, total orbitals,electrons

A

l=0,1,2,3,4
ml=0,-+1,-+2,-+3,+-4
25 (5 squared) orbitals
50 electrons

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3
Q

How does the radial probability plot and electron probability distribution look like

A

Goes up (1/4) and back down

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4
Q

how does the p orbitals look like?

A

two lobes and nucleus is on a plane that divides the lobes

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5
Q

how does d orbitals look like?

A

four lobes and one of them (dz2) has two and a ring

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6
Q

What are the 3 known electron configuaration anomolies

A

Cr, Cu, Mo
Chromium, Copper, Molybednum

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7
Q

diamagnetism

A

all of electrons are paired

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8
Q

paramagnetism

A

atoms with unpaired electrons

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9
Q

What 2 things make an atom bigger

NOT THE TREND, THE REASON

A

decreasing ZEFF, increasing electron electron repulsion making e- cloud bigger

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10
Q

What groups are the anomolies of IE in?

A

Group 3, 6

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11
Q

What groups is electron affinity +

and why

A

2,5 (just nitrogen), 8

energy must be added to add an additional electron

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12
Q

electronegativity of C,N,O,F (2nd period)

A

C: 2.5
N:3.0
O:3.5
F:4.0

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13
Q

Electronegativity of P, S, Cl (3rd period)

A

P: 2.2
S:2.6
Cl:3.0

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14
Q

Electronegativity of Br, I (4th and 5th halogens)

A

Br: 2.8
I:2.5

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15
Q

Ionic Compounds

  1. physical state
  2. melting and boiling point
  3. solubility in water
  4. Electrical Conductivity
A
  1. Exist as solids at room temp
  2. high melting and boiling
  3. dissolve in water
  4. do not conduct electricity in wolid state, does conduct in molten state
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16
Q

covalen compounds

  1. physical state
  2. melting and boiling point
  3. solubility in water
  4. Electrical Conductivity
A
  1. exist as gases, liquids, solids at room temp,
  2. low melting and boiling,
  3. do not dissolve in water,
  4. do not conduct electricity
17
Q

metallic

  1. physical state
  2. melting and boiling point
  3. solubility in water
  4. Electrical Conductivity
A
  1. exist as solids at room temp
  2. high melting and boiling temp
  3. do not dissolve in water
  4. good conductors of electricity in solid/molten
18
Q

Zinc charge

A

Zn2+

19
Q

Ammonium charge

A

NH4+

20
Q

nitrate

A

no3-

21
Q

sulfate

A

so42-

22
Q

phosphate!

A

po4 3-

23
Q

Carbonate

A

Co3 2-

24
Q

Perchlorate (4)

A

clo4-

25
Q

Acetate
C2H3O2

A

C2H3O2-

26
Q

Hypovalent molecules

A

Boron, beryllium, alluminum

27
Q

What is the most repulsive

A

Lone pair lone pair repulsions

28
Q

What is the least repulsive

A

Bond pair Bond pair repulsions

29
Q

Trigonal planar
makes what? SN?

A

SN=3, bent

30
Q

tetrahedral

A

SN=4 trigonal pyramidal, bemt

31
Q

trigonal byprimidal

A

SN=5 See Saw, T shape, Linear

32
Q

Octahedral

A

SN=6 Square pyramidal, square planar 90 degrees

33
Q

Polar bonds have

A

Dipole moments

34
Q

Sigma bond

A

head to head overlap ON internuclear axis

35
Q

Pi bonds

A

Side to side interlaps perpendicular to internuclear axis