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chem Flashcards

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1
Q

Cond Claisen

A

LDA, 25/-78, THF

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2
Q

Claisen Schmidtf

A

LDA, 25/-78, THF

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3
Q

Cond aldolica

A

LDA, 25/-78, THF

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4
Q

Natte

A

LDA, 25/-78, THF

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5
Q

Deickmann

A

LDA, 25/-78, THF

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6
Q

Sintesi Acetica

A

EtO- + calore

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7
Q

Sintesi Malonica

A

EtO- + calore

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8
Q

Base di Schiff

A

H+,H2O

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9
Q

Stork

A

H+,H2O

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10
Q

Knoevernagel

A

BuNH2

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11
Q

Mannich

A

HCHO, Ammina secondaria

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12
Q

Sir Robert Robinson Tropinone

A

H+,H2O, Calore

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13
Q

Anellazione di Robinson

A

Base Acide

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14
Q

TSHibibabin

A

NaNH2, NH3

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15
Q

Se Piridina

A
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16
Q

Hantzsch

A

H2O

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17
Q

Scramp

A

H+, DDQ

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18
Q

Paul-Knorr

A

NH3, P2O5

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19
Q

Fisher (indolo)

A

H+

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20
Q

Fisher Glucosio

A
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21
Q

Kiliam Fisher

A

HCN, Ba(OH)2, Na(Hg), o , HCN, Pd/BaSO4, H+

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22
Q

Degrqadaziojne di Wohl

A

NH2OH, Ac2O exc, Base,

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23
Q

Degradazione di Ruff

A
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24
Q

Hell Volhard Zelensky

A

PBr3, Br2

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25
Q

Immido malonati

A

EtO-, Br2, Potassioftalimmide, calore

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26
Q

Strecker

A

HCN, H+

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27
Q

Glicina

A
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28
Q

Alanina

A
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29
Q

Cisteina

A
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30
Q

Glutammina

A
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31
Q

Fenil alanina

A
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32
Q

Estere benzilico

A

basico neutro e acido trietilammina

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33
Q

BOC

A

Base, rilascio CF3CO2H trietilammina

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34
Q

Fmoc

A

rilascio cond basiche trietilammina

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35
Q

Stirene

A
36
Q

P iso Ninidrina

A
37
Q

Acido oleico

A
38
Q

Acido linoleico

A
39
Q

Acido linolenico

A
40
Q

Sasponificazione

A

Na2CO3——–> NaOH

41
Q

Fosfolipido

A
42
Q

FosfatidilColina

A
43
Q

Non saponificabili

A

Terpeni Trombossani prostaglandine Leucotrieni

44
Q

Terpeni

A
45
Q

Adenina`

A
46
Q

Guanina

A
47
Q

Citosina

A
48
Q

Timina

A
49
Q

Uracile

A
50
Q

trasp. cope

A
51
Q

trasp. Claisen

A
52
Q

Sabatier

A

H2, Pd/Pt/Rh

53
Q

Rid. Benzene

A

H2, Pd, 100Atm

54
Q

Cat. Lindlar

A

CaCO3, Pd, Chinolina, Pb(OAc)2

55
Q

Wilkinson

A

H2, ClRh(PPh3)3

56
Q

Rid. diazene

A

Per diazene, idrazina, Cu2+ O2, riduziojne idrazina,O2,Cu2+

57
Q

LiAlH4

A
58
Q

BH3

A
59
Q

Rosemond

A

H20, SOCl2, Lindlar, H2

60
Q

Cannizzaro

A

OH-

61
Q

Clark Eshuweiien

A

HCHO, HCOOH

62
Q

Bourandt blank

A

Na, EtOh

63
Q

Napinepen

A

Na, EtOH

64
Q

Brack

A

Li/Na/K, NH3 Liq

65
Q

Di idrossi accoppiamento

A

Mg(Hg), THF, H+

66
Q

Birch (alchino a alchene trans)

A

Li, NH3 liq

67
Q

Pinacolo e trasposizione pinacolica

A
68
Q

Prelog

A

4Na, Xilene, H+

69
Q

Clemmensen

A

Zn(Hg), HCl 37%

70
Q

WolfKishner

A

idrazina, KOH 20%, 1,2- etanolo 200gr

71
Q

Caglioti Vincenzo

A

toluenesolfonil idrazide, H+, NaBH4

72
Q

Riducente di Raney Ni/Ra`

A
73
Q

Permanganato

A

KMnO4, 0-5C

74
Q

Osmio

A

Ox= Ba(ClO3),tBuOOH, OsO4=catalizzatore

75
Q

epossidi

A

Perossiadidi, e doppi legami, o perossido, e stessa molecola per l’anellazione di robinson

76
Q

Epossidazione col vanadio

A

tBuOOH,VO(AcAc)

77
Q

Epossido, col titanio

A

tBuOOH,Ti(OCH(CH3)2)

78
Q

Cromo

A

HCrO4-, H2), o uso PCC (piridinio clorocromato)

79
Q

MnO2

Uso per ossidare alcoli allilici e benzilici

A
80
Q

Maffat

A

DMSO, PCC, dicicloesilimmide

81
Q

N cloro succinimmide

A

dimetil solfuro

82
Q

TEMPO fa da mediatore

A
83
Q

Riduzione Ammide

A

LiAlH4

84
Q

Apertura Epossido

A
85
Q

Epossido con Ozono

A
86
Q

Epossido con Ozono

A
87
Q

Chetoni con KMnO4

A

MnO4-, IO4-

chem (3 decks)

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