Chem 110 Final Flashcards
How to calculate the atomic mass?
Sum of (Isotopic mass times relative abundance of isotope) for each isotope
If energy is gained by the system and lost by the surroundings is the change in energy positive or negative?
Positive
If energy is lost by the system and gained by the surroudings is the change in energy positive or negative?
Negative
How to calculate formal charge?
Valence e - Lone e - Bonds
What is fusion?
Solid to liquid, which is positive
What is sublimation?
Solid to gas which is positive
Condensation?
Gas to liquid, negative VAP
Freezing?
Liquid to solid, Negative FUS
Deposition
Gas to solid, Negative SUB
Strong Acids are:
Hydrohalic acids starting with Cl and going down. (HCl, HBr)
Oxoacids where there are at least two more O atoms than there are ionizable H atoms (HNO3, HClO4)
Weak acids are:
Acids where H is not bonded to an O or a halide (HCN)
Ocoacids where there are less than two more O atoms than there are ionizable H atoms (HNO2 and HClO)
Organic Acids, (R-COOH)
Strong Bases
M2O and MOH, where M is any group 1 metal
M(OH)2 and MO where M is Ca, Sr or Ba
Weak Bases
Any compound with a lone electron pair on an N atom (NH3)
Using the Heats of Fortmation to determine Heats of Reaction?
Sum of moles of heat of formation of PRODUCTS minus sum of moles of heat of formation of REACTANTS
Using Bond Dissociation Energy to Calculate Heats of Reaction
Reactants minus Products
Using Stoichiometry to calc. Heats of Reaction
You may need to find the limiting reagent and find the lowest number moles.
Using Hess’s Law to calculate Heat of Reaction.
A + B = C, AH1
B+D=A+C, AH2
_______________
A+2B+D=A+2C
Cancel common facotrs.
Eq. Constants based on Pressure
A+B=C
Kp = (Pc)/ Pa * Pb
What happens if you increase the PRODUCTS?
The reactions proceeds RIGHT-LEFT, and more the REACTANTS INCREASE, and PRODUCT DECREASE
What happens if you DECREASE the REACTANTS?
The reaction proceeds right RIGHT-LEFT and more REACTANTS INCREASE AND PRODUCTS DECREASE
What happens when the pressure of PRODUCTS is incrreased?
SHIFTS REACTION RIGHT TO LEFT
What happens when the pressure of the reactants increasE?
SHIFTS REACTION LEFT TO RIGHT
If the total pressure increases?
The reaction proceeds in the direction with less moles of gas
If the total pressure decreases?
The reaction proceeds in the direction with more moles of gas