Chapters 18 & 19 Flashcards

0
Q

Electrophile

A

Needs more electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
1
Q

Nucleophile

A

More willing to give up electrons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Electrophiles are usually
A. Acids
B. Bases

A

A. Acids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Nucleophiles usually are
A. Acids
B. Bases

A

B. Bases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Curved arrows show the movement of electrons ALWAYS from the _____ to the _____

A

Nucleophile; Electrophile

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

The Nucleophile is the _____.

A

Base

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

The Electrophile is the _____.

A

Acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

The α (alpha) carbon is where?

A

The α carbon is the first carbon from the carbonyl group.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Carbonyl

A

C=O group

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Carbonyl groups are weak _____.

A

Nucleophiles

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Ketone Structure

A

R-(C=O)-R’

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Carboxylic Acid Structure

A

R-(C=O)-OH

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Ester Structure

A

R-(C=O)-O-R’

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Aldehyde Structure

A

R-(C=O)-H

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Acid Chloride Structure

A

R-(C=O)-Cl

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Amide Structure

A

R-(C=O)-NH2

16
Q

In a compound with two R groups, what does the R group stand for?

A

The R group is the same compound.

17
Q

R’ is what?

A

R’ can either be the same, or a different compound.

18
Q

In a compound with a ketone and an -OH group, what do you name as the substituent?

A

Name the -OH group as a hydroxy.

19
Q

(C=O)-H attached to a benzene is called what?

A

Benzaldehyde

20
Q

(C=O)-H not attached to a benzene, but is attached to a ring is called what?

A

Carbaldehyde

21
Q

Aldehyde priority is _____ than ketone.

A

Higher

22
Q

C=O as a substituent is called

A

Oxo

23
Q

Ketones as a substituent are called

A

Oxo

24
Q

Aldehydes as a substituent are called

A

Formyl

25
Q

CHO groups as a substituent are called

A

Formyl

26
Q

Common names for ketones use _____ instead of 1,2,3,4 etc.

A

α (alpha), β (beta), δ (delta), γ (gamma)

27
Q

What’s the common name for a 1 carbon aldehyde?

A

Formaldehyde

28
Q

What’s the common name for a 2 carbon aldehyde?

A

Acetaldehyde

29
Q

What’s the common name for a 3 carbon aldehyde?

A

Propionaldehyde

30
Q

What’s the common name for a 4 carbon aldehyde?

A

Butyraldehyde

31
Q

Carbonyl groups make the compound
A. More polar
B. Less polar
C. Stay the same

A

A. More polar