IR & Mass Spec Flashcards

0
Q

C-H stretch alkenes

A

3080-3020 cm-1

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1
Q

C-H stretch alkanes

A

2960-2850 cm-1

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2
Q

C-H stretch aromatic rings

A

3100-3000 cm-1

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3
Q

C-H stretch alkynes

A

3333-3267 cm-1

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4
Q

C=C stretch alkenes

A

1680-1640 cm-1

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5
Q

CΞC stretch alkynes

A

2260-2100 cm-1

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6
Q

C=C stretch aromatic rings

A

1600, 1500 cm-1

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7
Q

C-O stretch alcohols, ethers, carboxylic acids, & esters

A

1260-1000 cm-1

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8
Q

C=O stretch aldehydes, ketones, carboxylic acids, & esters

A

1760-1670 cm-1

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9
Q

O-H stretch (monomeric- bonded to another molecule) alcohols & phenols

A

3460-3160 cm-1

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10
Q

O-H stretch (hydrogen bonded) alcohols & phenols

A

3600-3200 cm-1

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11
Q

O-H stretch carboxylic acids

A

3000-2500 cm-1

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12
Q

N-H stretch amines

A

3500-3300 cm-1

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13
Q

C-N stretch amines

A

1340-1020 cm-1

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14
Q

CΞN stretch nitriles

A

2260-2220 cm-1

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15
Q

NO2 stretch nitro compounds

A

1660-1500 cm-1 asymmetrical stretch

1390-1260 cm-1 symmetrical stretch

16
Q

What is the nonlinear vibrational modes equation?

A

3n-6 (where n=# of total atoms in the molecule)

17
Q

C-C stretch

A

1200 cm-1

18
Q

C=C stretch

A

1660 cm-1

19
Q

CΞC stretch

A

2200 cm-1

20
Q

Isolated C=C stretch

A

1680-1640 cm-1

21
Q

Conjugated C=C stretch

A

1640-1620 cm-1

22
Q

Aromatic C=C stretch

A

1600 cm-1

23
Q

Molecular Ion

A

Mass of the whole molecule

24
Q

Br peak size

A

M+2 is equal to the M+

25
Q

Cl peak size

A

M+2 is 1/3 of M+

26
Q

I peak size

A

Peak at 127

27
Q

N peak size

A

M+ will be an odd number

28
Q

S peak size

A

M+2 will be 4% of M+

29
Q

Base peak

A

Is the largest/strongest peak. All other peaks are % of the base peak (the fragments).