Chapter Seven: Solutions Flashcards

1
Q

Normally, the body maintains a homeostasis of fluids and ______________. Conditions that alter the composition of body fluids can lead to _________, __________ or ________.

To halt the disease process and establish homeostasis, a patient may be given ______ _______ therapy.

A

electrolytes

convulsions, coma, death

intravenous fluid therapy

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2
Q

What is OSMOSIS?

A

Water flows in and out of the cells of the body

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3
Q

What is DIALYSIS?

A

Small particles in solution as well as water diffuse through semipermeable membranes.

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4
Q

The kidneys utilize OSMOSIS and DIALYSIS to regulate the amount of _______ and ___________ that are excreted.

A

Water and electrolytes.

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5
Q

What is a SOLUTION?

A

A homogeneous mixture in which one substance called the SOLUTE is uniformly dispersed in another substance called the SOLVENT.

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6
Q

Because the SOLUTE and the SOLVENT do not react with each other, they can be mixed in ______________ _______________.

A

varying proportions

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7
Q

Usually, the SOLUTE is the substance present in the _______ amount, whereas the SOLVENT is present in the ________ amount.

A

smaller

larger

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8
Q

In a solution, the particles of the SOLUTE are __________ dispersed among the molecules within the SOLVENT.

A

evenly

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9
Q

Which of the following may SOLVENTS and SOLUTES be: solids, liquids, gases?

A

All three

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10
Q

__________ is one of the most common SOLVENTS in nature.

A

Water

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11
Q

What is a POLAR SOLVENT? (use the example of water)

A

In the H2O molecule, an oxygen atom shares electrons with two hydrogen atoms. Because oxygen is much more electronegative than hydrogen, the O-H bonds are POLAR.

In each polar bond, the oxygen atom has a partial negative charge and the hydrogen atom has a partial positive charge.

Because the water molecule has a BENT shape, water is a POLAR SOLVENT

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12
Q

The _____________ between SOLUTE and SOLVENT will determine whether or not a solution will form.

A solution forms when _________________.

Such attractions only occur when the solute and the solvent have similar ____________.

A

Interaction

A solution forms when there is sufficient attraction between the particles of the solute and the solvent, which provides energy to separate the particles.

Polarities

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13
Q

SOLUTIONS with IONIC and POLAR solutes (use NaCl as an example):

There are __________ solute-solute attractions between positively charge Na+ ions and negatively charged CL- ions.

When NaCl crystals are placed in water, the process of ___________ begins as the partially _________ oxygen atoms in water molecules attract Na+ ions and the partially ________ hydrogen atoms in other water molecules attract CL- ions.

As soon as the Na+ and Cl- ions form a solution, they undergo ___________ as water molecules surround each ion. This diminishes their attraction to other ions and keeps them in solution.

The energy needed to form the solution is provided by the strong solute-solvent attractions between _____________ and the ______________.

A

strong solute-solute attractions

DISSOLUTION; negative, positive

HYDRATION

The energy needed to form the solution is provided by the strong solute-solver attractions between Na+ and Cl- ions and the polar water molecules.

See the equation for the formation of the NaCl solution on page 249.

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14
Q

A POLAR COVALENT COMPOUNDS such a methanol (CH3-OH) is soluble in water because ______________.

A

because methanol has a polar -OH group that forms hydrogen bonds with water.

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15
Q

Compounds containing NONPOLAR molecules such as iodine (I2), oil or grease do not dissolve in water because _______.

NONPOLAR solutes require ____________ solvents for a solution to form.

The _________ of a solute and a solvent must be similar in order to form a solution.

A

because there are essentially no attractions between the NONPOLAR solute and the POLAR solvent.

See Table 7.3 on page 249- possible combinations of solutes and solvents.

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16
Q

Solutes can be classified by their ability to conduct an electrical current.

When solutes called ELECTROLYTES dissolve in water, they separate into ions forming solutions that are __________ to conduct electricity.

When NONELECTROLYTES dissolve in water, they dissolve as molecules, not as ions and the solutions formed are _________ to conduct electricity.

A

ELECTROLYTES: able to conduct electricity

NONELECTROLYTES: NOT able to conduct electricity.

NOTE- to test solutions for the presence of ions, an apparatus is used that consists of a battery and a pair of electrodes connected by wires to a light bulb. The light bulb glows when electricity can slow, which can only happen when electrolytes provide ions that move between the electrodes to complete the circuit.

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17
Q

All ELECTROLYTES under _____________, in which some or all of the solute that dissolves produces ions.

A

DISSOCIATION

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18
Q

For a STRONG ELECTROLYTE, such as NaCl, there is _________ % dissociation of the solute into ions. The light bulb is ______.

A

100%; very bright

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19
Q

In an equation for dissociation of a compound in water, the charges must _________.

A

the charges must BALANCE.

See equation on page 251

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20
Q

What is a WEAK ELECTROLYTE?

A

…a compound that dissolves in water mostly as molecules. Only a few of the dissolved molecules separate, producing a small number of ions in solution.

Electrical current is not conducted as well as solutions of strong electrolytes.

See the equation on page 251.

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21
Q

What happens to a NONELECTROLYTE when it dissolves in water?

A

It dissolves only as molecules which do not separate into ions. These solutions do NOT conduct electricity.

See the chart on page 252- classification of solutes in aqueous solution.

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22
Q

What is an EQUIVALENT (Eq) ?

A

Body fluids contain a mixture of several electrolytes. We measure each individual ion in terms of an EQUIVALENT (Eq), which is the amount of that ion equal to 1 mole of positive or negative electrical charge.

Ex: 1 mole of Na+ ions and 1 mole of Cl- ions are each 1 equivalent because they each contain 1 mole of charge. For an ion with a charge of 2+ or 2-, there are 2 equivalents for each mole.

See Table 7.5 on page 252- equivalents of electrolytes

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23
Q

In any solution, the charge of the positive ions is ___________ balanced by the charge of the negative ions.

A

always

24
Q

The concentrations of electrolytes in intravenous fluids are expressed in ________ per liter

1 Eq= 1000 _______

A

milliequivalents per liter (mEq/L)

1 Eq= 1000 mEq

25
Q

What is SOLUBILITY?

What affects it?

How is it usually expressed?

A

The term SOLUBILITY is used to describe the amount of a SOLUTE that can dissolve in a given amount of SOLVENT at a certain temperature.

Many factors such as the type of solute, the type of solvent and the temperature affect the SOLUBILITY of a solute.

Usually expressed in grams of solute in 100 grams of solvent.

26
Q

What is an UNSATURATED SOLUTION?

What is a SATURATED SOLUTION?

What is RECRYSTALLIZATION?

A

UNSATURATED SOLUTION: If a solute readily dissolves when added to the solvent, the solution does not contain the maximum amount of solute.

SATURATED SOLUTION: A solution that contains all the solute that can dissolve.

RECRYSTALLIZATION: When a solution is saturated, the rate at which the solute dissolves becomes equal to the rate at which solid forms. Then there is no further change in the amount of dissolved solute in solution.

27
Q

How do we prepare a SATURATED SOLUTION?

A

…by adding an amount of solute greater than that needed to reach solubility. Stirring the solution will dissolve the maximum amount of solute and leave the excess on the bottom of the container.

Once we have a matured solution, the add-on of more solute will only increase the amount of undissolved solute.

28
Q

The solubility of most solids is _________ as TEMPERATURE increases, which means that solutions usually contain _______ dissolved solute at higher temperature.

A

greater, more

NOTE: a few substances show little change in solubility at higher temps, and a few are less soluble.

29
Q

What is a SUPERSATURATED solution?

A

When a saturated solution is carefully cooled, it becomes a SUPERSATURATED solution because it contains more solute than the solubility allows.

It is UNSTABLE and if the solution is agitated or if a solute crystal is added, the excess solute will recrystallize to give a saturated solution again.

30
Q

The solubility of a GAS in water ________ as the temperature increases. Explain…

A

Decreases

At higher temps, more gas molecules have the energy to escape from the solution.

31
Q

What is Henry’s Law?

A

It states that the solubility of gas in a liquid is directly related to the pressure of that gas above the liquid. At higher pressures, there are more gas molecules available to enter and dissolve in the liquid.

See page for an example

32
Q

What are SOLUBLE SALTS?

What are INSOLUBLE SALTS?

A

Soluble salts- Ionic compounds that dissolve in water.

Insoluble salts- Some ionic compounds do not separate into ions in water- they remain solids.

33
Q

Salts that are soluble in water typically contain at least one of which 6 ions (4 positive and 2 negative)?

A

Li+
Na+
K+
NH4+

NO3-
C2H3O2- (acetate)

34
Q

Most salts containing Cl- are _____

AgCl, PbCl2 and Hg2Cl2 are _____ salts

A

Soluble

Insoluble

35
Q

Most salts containing SO4^2- are _______, but a few are _________

A

soluble, insoluble

See table 7.8 on page 258

NOTE: most other salts are INSOLUBLE (do not dissolve in water)

36
Q

In an INSOLUBLE salt, attractions between its positive and negative ions are _________ and the polar molecules _______ break.

A

too strong; don’t

37
Q

We can use the SOLUBILITY RULES to predict ___________

A

whether a salt (a solid ionic compound) would be expected to dissolve in water.

See Table 7.8 on page 258 and Table 7.9 on page 259.

38
Q

How do we define the CONCENTRATION of a solution?

How is the concentration expressed?

A

The amount of solute dissolved in a certain amount of solution is called the CONCENTRATION of the solution.

Expressed as a ratio of a certain amount of solute (in units of grams, milliliters or moles) in a given amount of solution (in units of grams, milliliters or liters).

Concentration of a solution=
amount of solute/amount of solution

39
Q

What is MASS PERCENT (m/m)?

In the calculation of mass percent, what must be the same?

The mass of the solution is the sum of what 2 things?

A

MASS PERCENT (m/m) describes the mass of the solute in grams for exactly 100 g of solution.

The units of mass of the solute and the solution must be the same.

The mass of the solution is the sum of the mass of the solute and the mass of the solvent.

See page 260 for the formula for calculating solution concentration.

40
Q

What is the VOLUME PERCENT (v/v)?

A

because the volumes of liquids or gases are easily measured, eh concentrations of their solutions are often expressed as VOLUME PERCENT (v/v). The units of volume used in the ratio must be the same.

We interpret a volume percent as the volume of solute in exactly 100mL of solution.

See page 261 for the formula for calculating volume percent concentration.

41
Q

What is MASS/VOLUME PERCENT (m/v)?

A

It describes the mass of the solute in grams for exactly 100 mL of solution.

In the calculation of mass/volume percent, the uni of mass of the solute is grams and the unit of volume is milliliters.

See page 262 for the formula for calculations.

42
Q

What is MOLARITY (M)?

A

When chemists work with solutions, they often use MOLARITY (M), a concentration that states the number of moles of solute in exactly one liter of solution.

Molarity (M)=
moles of solute/liters of solution

The molarity of a solution can be calculated knowing the moles of solute and the volume of solution in liters. See example on page 262.

43
Q

In the preparation of solutions, we often need to calculate the amount of solute or volume of solution. Then the concentration is useful as a ___________ ___________.

A

conversion factor.

See Table 7.11 on page 264

44
Q

Describe the process called DILUTION.

Although the addition of solvent increases the volume, the amount of solute in the diluted solution is equal to ___________________. How do we write this equality?

A

In chemistry and biology, we often prepare diluted solutions from more concentrated solutions.

In a process called DILUTION: a solvent, usually water, is added to a solution, which increases the volume. As a result, the concentration of the solution DECREASES. (Example: OJ)

The amount of solute in the diluted solution is equal to the amount of solute present before dilution. We can write this equality in terms of the concentration, C (in percent concentration or molarity), and the volume, V (italicized). See page 266.

45
Q

Properties of SOLUTIONS:
* The solute is dissolved as SMALL particles that are _________ dispersed throughout the solvent to give a __________ solution.

  • The solution appears ___________ because you cannot visually distinguish the solute from the solvent.
  • The particles are so small that they go through filters and through _________ membranes.
A

uniformly; homogenous

transparent

semipermeable

46
Q

Properties of COLLOIDS:
* Solute particles are LARGE molecules, such as _____ or groups of ______ or _______.

  • They are ___________ mixtures that do not separate or settle out.
  • Particles are small enough to pass through ______ but too large to pass through _____ _______.
A

proteins; molecules or ions

homogenous

filters; semipermeable membranes

See Table 7.12 on page 270 for examples of colloids

47
Q

What are SUSPENSIONS?

PROPERTIES of SUSPENSIONS?
* The particles of a suspension are so LARGE that they can often be __________.

  • Can they go through filters and semipermeable membranes?
  • The weight of the suspended solute particles causes them to ___________.
A

Suspensions are heterogenous, nonuniform mixtures that are very different from solutions or colloids.

  • seen with the naked eye.
  • no, they are trapped by them.
  • settle out soon after mixing.

See Table 7.13 on page 270- comparison of solutions, colloids and suspensions

48
Q

What are COLLIGATIVE PROPERTIES?

A

When a solute dissolves in water, the particles in the solution affect the physical properties such as freezing point and boiling point.

Any aqueous solution will have a lower freezing point and a higher boiling point an pure water.

These types of changes in physical properties are examples of COLLIGATIVE PROPERTIES, which depend only on the number of solute particles in the solution.

Examples: salt on icy sidewalks; antifreeze

49
Q

How does the lowering of the freezing point of water occur when solute is added?

A

The solute particles disrupt the formation of the solid ice structure. Thus, a lower temp is required to freeze the water in the solution.

The greater the solute concentration, the lower the freezing point will be.

50
Q

How does the raising of the boiling point of water occur when solute is added?

A

The solute particles disrupt the formation of water vapor.

51
Q

What is OSMOSIS?

A

Water molecules move through a semipermeable membrane from the solution with the lower concentration of solute into a solution with the higher solute concentration.

52
Q

What is OSMOTIC PRESSURE? (explain how this works in an osmosis apparatus)

A

Water is placed on one side of a semipermeable membrane and a sucrose (sugar) solution on the other side. The membrane allows water molecules to flow back and forth, but blocks the sucrose molecules (too large to pass through).

Because the sucrose solution has a higher solute concentration, more water molecules flow into the sucrose solution than out of it. the volume level of the sucrose solution rises as the volume level on the water side falls. the increase of water dilutes the sucrose solution to attempt to equalize the concentrations on both sides.

Eventually the height of the sucrose solution creates sufficient pressure to equalize the flow of water between the 2 compartments. This is the OSMOTIC PRESSURE and it prevents the flow of additional water into the more concentrated solution.

The greater the number of particles dissolved, the higher its osmotic pressure.

53
Q

What is REVERSE OSMOSIS?

A

In this process, a pressure grater than the osmotic pressure is applied to a solution. The flow of water is reversed so that the water flows out of the solution with the higher solute concentration.

This is used in desalination plants to obtain pure water from sea (salt) water.

54
Q

What are ISOTONIC SOLUTIONS?

What is the PERCENT CONCENTRATION typically used in IV solutions?

A

Because the cell membranes in biological systems are semipermeable, osmosis is an ongoing process. The solutes in blood, tissue fluids, lymph, plasma, etc. all exert osmotic pressure.

Most intravenous solutions used in a hospital are ISOTONIC SOLUTIONS, which exert the same osmotic pressure as body fluids such as blood.

The percent concentration typically used in IV solutions is MASS/VOLUME percent (m/v).

55
Q

What is a HYPOTONIC SOLUTION and what happens when a red blood cell is placed in it?

Describe HEMOLYSIS.

A

When a red blood cell is placed in a HYPOTONIC SOLUTION, which has a lower solute concentration, water flows into the cell by osmosis.

The increase in fluid causes the cell to swell, and possibly burst (HEMOLYSIS).

This is similar to what happens when you place dehydrated foods in water. the water enters the cells and the food becomes plump and smooth.

56
Q

What is a HYPERTONIC SOLUTION and what happens when a red blood cell is placed in it?

Describe CRENATION.

A

If a red blood cell is placed in a HYPERTONIC SOLUTION, which has a higher solute concentration, water goes out of the cell into the hypertonic solution by osmosis.

As water leaves the cell, it shrinks in a process called CRENATION.

This is similar to what happens when making pickles when a hypertonic salt solution causes the cucumbers to shrivel as they lose water.

57
Q

What is DIALYSIS?

A

It is a process that is similar to osmosis.

A semipermeable membrane, called a dialyzing membrane, permits small solute molecules and ions as well as solvent water molecules to pass through, but it retains large particles, such as colloids.

Dialysis is a way to separate solution particles from colloids. See the example describe on page 276.