Chapter 9 Flashcards
Molecular Geometry
3-D arrangement of atoms in a molecule
AX2
Linear
180
AX3
Trigonal Planar
120
AX4
Tetrahedral
109.5
AX5
Trigonal Bipyramidal
90, 120, 180
AX6
Octahedron
90, 180
VSEPR Theory Meaning
Valence Shell Electron Pair Repulsion Theory
VSEPR Theory
Valence electron pairs in a molecule repel each other, and so try to position themselves as far as possible away from each other
What is the molecular geometry controlled by?
Repulsion between electron pairs
Rules in VSEPR Model
When counting electron pairs around the central atom, lone pairs, double and triple bonds are all treated just like single bonds
If a molecules has more than one resonance structure, then the VSEPR model can be applied to any one of them
Order of Repulsion Energies
LP/LP > LP/BP > BP/BP
Lone pairs are bigger and push the bond angles of the structures
AX2E
Bent
AX3E
Trigonal Pyramidal
AX2E2
Bent
AX4E
Seesaw