Chapter 8 - Reuduction and oxidation Flashcards
Oxidation refers to
gaining oxygen, losing hydrogen, or losing one or more electrons.
Reduction refers to
losing oxygen, gaining hydrogen, or gaining one or more electrons.
In an electrolytic cell,
the passage of an electrical current through an electrolyte causes a chemical reaction to occur.
In a galvanic cell,
a spontaneous redox reaction occurs and generates an electrical current.
An oxidation process is accompanied by
an increase in the oxidation state of the element involved.
A reduction process is accompanied by
a decrease in the oxidation state of the element involved.
The net change in oxidation states for the oxidation and reduction steps in a given reaction must
balance.
Faraday constant
96485 C/mol
For a thermodynamically favored cell reation:
Eocell is positive
deltaGo is negative
K > 1
For a spontaneous reaction, the value of Eocell is always
positive.
The overpotential is
the additional potential above the value required by thermodynamics to initiate a reaction at an electrode.