Chapter 8 Reagents Flashcards by Grace Bryan | Brainscape

Q

addition of HX to alkene

A

HX, Ether

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Q

halogenation of alkenes

A

X2, CH2Cl2

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Q

Halohydrin formation

A

X2, H2O

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Q

Oxymercuration

A

1.Hg(OAc)2, H2O/THF 2.NaBH4

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Q

hydroboration

A

1.BH3, THF 2.H2O2,OH-

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Q

hydrogenation

A

H2, Pd/C or PtO2

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Q

Epoxidation

A

RCOOH (double O on the C)

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Q

Hydroxylation

A

OsO4 2.NaHSO3,H2O or OsO4,NMO

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Q

dichlorocarbene addition

A

CHCl3, KOH

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Q

Simmons-Smith rxn

A

CH2I2, Zn(Cu) & Ether

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Q

Hydroxylation by acid-catalyzed epoxide hydrolysis

A

H3O+

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Q

Oxidative cleavage via ozone

A

O3 2.Zn/H3O+

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Q

Oxidative cleavage via potassium permanganate

A

KMnO4, H3O+

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Q

Cleavage of 1,2-diols

A

HIO4, H2O

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Q

Dehydrohalogenation

A

KOH, Ethanol

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Q

Dehydration

A

H2SO4, H2O THF 50 degrees celsius