Chapter 8: Alkene reactions Flashcards
1
Q
Markonikov Hydrohalogenation
A
HBr
2
Q
Anti-Markovnikov Hydrohalogenation
A
HBr with ROOR
3
Q
Acid-Catalyzed Hydration
A
H3O +
4
Q
Oxymercuration demercuration
A
(1) Hg(OAc)2, H2O
(2) NaBH4
5
Q
Anti-Markovnikov addition via Hydroboration Oxidation, syn addition
A
(1) BH3 . THF
(2) H2O2, NaOH
6
Q
Halogenation
A
Br2 in CHCl3
7
Q
Halohydrin Formation
A
Br2 and H2O
8
Q
Anti Dihydroxylation
A
(1) RCO3H
(2) H3O +
9
Q
Syn Dihydroxylation
A
(1) OsO4
(2) NMO or peroxide
OR
KMnO4, NaOH
10
Q
Oxidative Cleavage
A
(1) O3
(2) DMS