chapter 8 Flashcards

1
Q

shows the particular orbitals that electrons occupy for the atom

A

electron configuration

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2
Q

represent the lowest energy state for electrons

A

ground state electron configurations

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3
Q

no two electrons in an atom may have the same self four quantum numbers.
this means no orbital can hold more than two electrons

A

pauli exclusion principle

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4
Q

when two electrons occupy the same orbital, they are

A

spin paired

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5
Q

like charges repel and opposite charges attract

A

coulomb’s law

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6
Q

the masking of nuclear charge by other electrons

A

shielding

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7
Q

the charge felt by electrons in comparison to the actual nuclear charge

A

effective nuclear charge

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8
Q

when an electron penetrates the electron cloud and moves closer to the nucleus, it experiences

A

the full positive charge of the nucleus

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9
Q

orbitals should be filled starting with the lowest energy orbitals and proceeding to higher energy orbitals

A

auf bau principle

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10
Q

each degenerate orbital will have one electron in it before any electrons are paried

A

hund’s rule

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11
Q

the spins in singly occupied orbitals remain parallel until the second electron enters the orbital

A

hund’s rule

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12
Q

the inner electrons which lie closer to the nuclues

A

core electrons

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13
Q

outer electrons

A

valence electrons

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14
Q

periodic trends are based largelyy on

A

effective nuclear charge

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15
Q

all atoms lose their ________ first to form cations

A

highest energy electrons

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16
Q

for ns electrons, the ns electrons are lose _______ the (n-1)d electrons

A

before

17
Q

cations cause the electron radius to go

A

smaller

18
Q

anions cause the electron radius to

A

increase

19
Q

electrons are held more tightly from ______ to _____ across a period

A

left to right

20
Q

the minimum energy needed to remove an electron from a neutral atom in the gas phase

A

first ionization energy

21
Q

first ionization energy increases how, periodic trend?

A

up a group and from left to right across a period

22
Q

is associated with removing a second electron this Time from a 1+ ion

A

second ionization energy

23
Q

the energy released when an electron Is added to a gas-phase atom

A

electron affinity

24
Q

general trend shows that oxygen should have a higher first ionization energy than ____ but it does not

A

nitrogen

25
Q

what is special about the electron configuration of nitrogen

A

it has one unpaired electron in each of the three 2p orbitals

26
Q

all group 5A elements invert first ionization energy order with the group ____ element in their row

A

6A

27
Q

all group 5A elements invert electron affinity order with the group ____ element in their row

A

4A