chapter 8 Flashcards
shows the particular orbitals that electrons occupy for the atom
electron configuration
represent the lowest energy state for electrons
ground state electron configurations
no two electrons in an atom may have the same self four quantum numbers.
this means no orbital can hold more than two electrons
pauli exclusion principle
when two electrons occupy the same orbital, they are
spin paired
like charges repel and opposite charges attract
coulomb’s law
the masking of nuclear charge by other electrons
shielding
the charge felt by electrons in comparison to the actual nuclear charge
effective nuclear charge
when an electron penetrates the electron cloud and moves closer to the nucleus, it experiences
the full positive charge of the nucleus
orbitals should be filled starting with the lowest energy orbitals and proceeding to higher energy orbitals
auf bau principle
each degenerate orbital will have one electron in it before any electrons are paried
hund’s rule
the spins in singly occupied orbitals remain parallel until the second electron enters the orbital
hund’s rule
the inner electrons which lie closer to the nuclues
core electrons
outer electrons
valence electrons
periodic trends are based largelyy on
effective nuclear charge
all atoms lose their ________ first to form cations
highest energy electrons
for ns electrons, the ns electrons are lose _______ the (n-1)d electrons
before
cations cause the electron radius to go
smaller
anions cause the electron radius to
increase
electrons are held more tightly from ______ to _____ across a period
left to right
the minimum energy needed to remove an electron from a neutral atom in the gas phase
first ionization energy
first ionization energy increases how, periodic trend?
up a group and from left to right across a period
is associated with removing a second electron this Time from a 1+ ion
second ionization energy
the energy released when an electron Is added to a gas-phase atom
electron affinity
general trend shows that oxygen should have a higher first ionization energy than ____ but it does not
nitrogen