Chapter 7 - Periodicity Flashcards
What is ionisation energy?
Ionisation energy measures how easily an atom loses electrons to form positive ions
What is the first ionisation energy?
The energy required to remove one electron from each atom in one mole of gaseous atoms of an element to form one mole of gaseous 1+ ions
What factors affect ionisation energy?
-Atomic radius - the greater the distance the less the nuclear attraction so decreases the ionisation energy with a larger atomic radius
-Nuclear charge - The more protons in the nucleus of the atom, the greater the attraction between nucleus and electrons, so higher activation energy
-Electron Shielding - Electrons are -ve charged so inner shell electrons repel outer shell electrons (shielding effect) this reduces the attraction between the nucleus and the outer shell electrons.
What is metallic bonding?
The strong electrostatic attraction between cations and delocalised electrons
What structure do metals have?
Giant metallic lattice
What physical properties do most metals have?
-Electrical conductors - can conduct when both solid and liquid, the delocalised electrons can move through the structure and carry charge
-High melting and boiling points - high temperature is required to provide enough energy to overcome the strong electrostatic attraction between cations and electrons
-Not soluble
What are the properties of substances with a giant covalent lattice structure?
-High melting and boiling points - they are held together by strong covalent bonds which require high temperatures to overcome
-Insoluble
-Do not conduct electricity - (except graphite / graphene) they have no available electrons that can move to carry current