Chapter 7: Organic chemistry Flashcards
What is the functional group?
The atoms in a molecule which give it its chemical reactivity (e.g. C=C)
What is a homologous series?
A series of molecules with the same functional group but where each successive member differs by a CH2 unit
What is are the prefixes for members of homologous series?
1 x Carbon= Meth-, 2= Eth-, 3= Prop- 4=But-
What is the functional group for alkanes?
They don’t have one
What is the functional group for alkenes?
C=C
What is the functional group for alcohols?
-OH bound to a carbon
What is the functional group for carboxylic acids?
H-O-C=O (clockwise)
What is the functional group for esters?
O=C-O
What happens when an alkene reacts with a halogen (halogenation)?
The C=C double bond breaks and the carbons bond to halogen atoms
What happens when an alkene reacts with hydrogen (hydrogenation)?
The C=C double bond breaks and each carbon gains an extra hydrogen (nickel catalyst and 150 degrees required)
What happens when an alkene reacts with water (hydration)?
It turns into the equivalent alcohol (H3PO4, high pressure and high temperature required)
What is the naming scheme for esters?
Xanol + Yanoic acid -> Xyl Yanoate + Water
How do alcohols react with water?
Small alcohols dissolve in water to form a neutral solution
What happens when you combust alcohols?
They burn readily with a clean flame, producing CO2 and H2O
How do alcohols react with sodium?
They produce hydrogen
How do alcohols react with oxygen?
They slowly turn into their equivalent carboxylic acid
How do alcohols react with carboxylic acids?
They produce water and an ester (in the presence of an acid catalyst)
How do carboxylic acids react with carbonates?
They make CO2, H2O and the CHxCOO part bonds with the calcium
What is a condensation reaction?
One where water is formed
What are polymers?
Long chain molecules made from joining smaller molecules together
What reactions create polymers?
Addition reactions, condensation reactions
What happens during addition polymerisation?
The C=C double bonds break and the molecules join onto each other