Chapter 7 Flashcards

0
Q

Surrounding

A

The rest of the universe

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1
Q

System

A

Contains the process under study

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2
Q

First law of thermodynamics

A

Energy of the universe is constant (law of conservation)

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3
Q

Each chemical bond has what?

A

Stored chemical energy

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4
Q

Exothermic reaction

A

Energy required to break the bond is less than than the energy released when the bonds are formed, net release of energy

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5
Q

Endothermic reaction

A

Energy required to break bonds is larger than the energy released when the bonds are formed

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6
Q

Entropy is negative you must do what?

A

Apply some form of energy

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7
Q

2nd law of thermodynamics

A

Spontaneous

Doubly tends toward increasing disorder and randomness

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8
Q

Entropy

A

Measure of randomness of a chemical system (no such thing as negative entropy)

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9
Q

Positive entropy means?

A

Increase in disorder for the reaction

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10
Q

Exothermic and positive entropy =

A

Spontaneous

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11
Q

Endothermic and negative entropy =

A

Non spontaneous

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12
Q

Free energy

A

Represents the combined contribution of the enthalpy n entropy values for a chemical reaction

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13
Q

Free energy predicts what?

A

Spontaneity of a chemical reaction

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14
Q

Calorimetry

A

Measurement of heat energy changes in a chemical reaction

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15
Q

Calorimeter

A

Measures heat changes in calories

16
Q

Specific heat (sh)

A

of calories if heat needed to raise the temperature of 1g of the substance 1degree C