Chapter 6: Equilibrium Flashcards

1
Q

At any point during a reaction, we can measure the concentrations of all of the reactants and products and calculate the ____________ ____________.

A

reaction quotient

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2
Q

When K < Q, which was does the reaction go?

A

To the left, towards the reactants (too much product)

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3
Q

When K = Q, the reaction is at ____________ and the forward and reverse rates are ________.

A

equilibrium, equal

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4
Q

When K > Q, which way does the rxn go?

A

Towards the product, forward rate

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5
Q

The larger the value of Keq, the farther to the ________ the equilibrium position.

A

right

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6
Q

If equilibirum constant for a reaction written in one direction is Keq, the equilibirum constant for the reverse is what?

A

1/Keq

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7
Q

A reaction that strongly favors products will have what eq exponent?

A

a large, positive one

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8
Q

If pressure is increased, the reaction will move toward which direction?

A

Whichever side has less moles of gas

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9
Q

If a reaction is ____________, heat functions as a reactant. If exothermic, heat is a ____________.

A

endothermic, product

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10
Q

At lower temperatures (with smaller heat transfer), a ____________ product is formed. It is formed faster.

A

kinetic

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11
Q

At higher temperatures (with larger heat transfer), a ____________ product is formed. It is more stable.

A

thermodynamic

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12
Q

Which forms faster, kinetic or thermodynamic products? Why?

A

Kinetic products; the free energy that must be added for the kinetic pathway is lower than that of the thermodynamic pathway

See p212

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