Chapter 6: Chemical Reactions Flashcards
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What is a Chemical Reaction?
- A process in which one or more reactants, are converted to one or more different products.
- Occur when chemical bonds between atoms are formed or broken
- A chemical reaction rearranges the atoms of the reactants to create different products.
reactants 🡢 products
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What is Chemical Equation?
- Detailed information to describe any chemical reaction
- Reactions can be represented using words or symbols; which display all the reactants, products and other relevant information
Word Equation vs Formula Equation
Worded Equation: calcium carbonate + sulphuric acid 🡢 calcium sulphate + carbon dioxide gas + water
Formula Equation: CaCO3 + H2SO4 🡢 CaSO4 + CO2 + H2O
Products vs Reactants
- Reactants: LHS; starting substances (e.g. calcium carbonate and sulphuric acid)
- Products: RHS; end substances (e.g. calcium sulphate, carbon dioxide gas, and water)
States of Matter
- Solids (s)
- Liquids (l)
- Gas (g)
- Aqueous (aq) (disolved in water)
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How to Identify a Chemical Change?
- Change in colour
- Smelling a gas or bubbles
- New solid (precipitate) formed in a clear solution
- Energy is absorbed or produced in the form of heat or light
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How to Identify a Physical Change?
- Chemical nature is not altered; nothing new is produced
- However, there may be a change in state (solid, liquid, gas), size, and shape
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Law of Conservation of Mass
- “The Mass of a completely isolated system will remain constant”
- Total Mass of Reactants = Total Mass of Products
- Mass cannot be created or destroyed, only rearranged or transformed
Balancing Chemical Reactions
Example (propane + oxygen)
* C3H8 + O2 🡢 H2O + CO2
LHS: 3 carbons, 8 hydrogens, 2 oxygens
RHS: 1 carbon, 2 hydrogens, 3 oxygens
Becomes…
C3H8 + 5O2 🡢 4H2O + 3CO2
LHS: 3 carbons, 8 hydrogens, 10 oxygens
RHS: 3 carbon, 8 hydrogens, 10 oxygens
Hydrogen (H2) gas + oxygen gas (O2) 🡢 pure water (H2O)
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What is Chemical Energy?
- Energy stored in the chemical bonds of a substance
- Chemical reactions always involve energy changes as making bonds and breaking bonds involve energy changes
- All molecules store energy in the form of chemical potential energy
- However, during a chemical reaction the atoms in the molecules are rearranged and so energy may be released
Chemical potential energy: energy from fossil fuels, batteries, and food
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Activation Energy
For all chemical reactions, activation energy is the energy supplied to break the bonds of the reactants for a chemical reaction to occur
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Steps for Endothermic or Exothermic Reaction
- Step 1: Energy must be SUPPLIED to break chemical bonds of reactants
- Step 2: Energy is RELEASED when new chemical bonds are formed in the products
*A reaction is exothermic if more energy is released than supplied. If more energy is supplied than is released, then the reaction is endothermic *
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Difference between Exothermic and Endothermic
- All reactions (exothermic and endothermic) first require energy from surroundings to break bonds in the reactant molecules and secondly make bonds to form new product molecules therefore releasing energy back into the surroundings.
- The difference is whether the amount of energy released when the new bonds form is greater or less than the energy required to break the old bonds.
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Exothermic
- Reactions that release energy
- More energy is released when the bonds are formed in the products, than energy used to break bonds in the reactants. Therefore, a net release of energy.
- Heat (energy) given off; temperature of the substance rises; HOT
Reactants 🡢 products + energy or heat
* E.g. burning of gasoline
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Endothermic
- Reactions that absorb energy
- More energy is absorbed to break the bonds in the reactants than released by the bonds being formed in the products. Therefore, energy is absorbed.
- Heat (energy) taken in; temperature of the substance drops; COLD
*Reactants + energy or heat 🡢 products
* E.g. cooking of pancakes
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Examples of Exothermic Reactions
- Combustion of fuels
- Yeast & Hydrogen Peroxide
- Epson salts & water
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Examples of Endothermic Reactions
- Photosynthesis
- Acedic Acid & Sodium Bicarbonate
Reactions with oxygen tend to be…
Exothermic