Chapter 6: Chemical reaction: energy, rates, and equilibuim Flashcards

1
Q

biomolecules react with

A

oxygen to produce co2 and h2o

going from a high potential energy to a low

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2
Q

1 cal=

A

hear energy required to raise the temp. of 1 gram of water by 1 c

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3
Q

Keq=

A

equilibrium constant

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4
Q

constants in an equilibrium equation

A

solids and liquids

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5
Q

homogeneous

A

same (g=g+g)

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6
Q

Heterogeneous

A

different (s=aq+aq)

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7
Q

p=

A

nRT/(V)

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8
Q

pressure and volume are BLANK related

A

Inversely

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9
Q

The first law of thermodynamic

A

-energy can be neither created nor destroyed; energy is conserved

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10
Q

Exothermic characters

A

Surrounding get warmer
reactants have higher potential energy than products
(-) sign
making a bond

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11
Q

Endothermic characters

A

surrounding gets cooler
reactants have lower potential energy than the products
(+) sign
breaking a bond

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12
Q

higher bond energies=

A

stronger bond with lower potential energies

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13
Q

weaker bonds=

A

more ractive

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14
Q

types of biomolcules

A

carbohydrates, proteins, fats

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15
Q

Biochemical pathway=

A

the sequence of reactions leading to a particular product

catabolic, Anabolic

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16
Q

Catabolic Pathways

A

convert large molecules into smaller ones
break down biomolecules from diet
release energy in special energy ( ATP)

17
Q

Anabolic pathways

A

build larger molecules from smaller ones
build proteins, lipids, and DNA
use energy from catabolism

18
Q

Activation energy

A

Amount of energy that must be attained by reactants for a chemical reaction to occur.

19
Q

larger activation energy =

A

bigger hill and slower reaction

20
Q

heat energy causes

A

particles to move faster and have higher kinetic energy

21
Q

Biological catalysts are called

A

Enzymes

22
Q

Keq> 1

A

products favored

23
Q

Keq <1

A

reactant favored

24
Q

Le chatelier’s principle

A

if a stress is applied to a system at equilibrium, the reaction will ten to shift in a direction to release that stress.