Chapter 6 Flashcards
Exothermic Reaction
A reaction that gives out energy and is accompanied by a temperature increase. There are bonds formed in an exothermic reaction.
Endothermic Reaction
A reaction that takes in energy and is accompanied by a temperature decrease. There are bonds broken in an endothermic reaction.
Exothermic Energy Level Diagrams
There are more reactants than products. An example is the combustion of hydrogen to form water.
Endothermic Energy Level Diagrams
There are less reactants than products. An example is the decomposition of calcium carbonate.
Enthalpy Change
The difference in energy between the reactants and products of a reaction. kJ/mol. Δ H = energy of bonds broken – energy of bonds formed.
Exothermic Enthalpy Change
-∆H. In an exothermic reaction, the energy released when new bonds form is greater than the energy needed to break them so the surplus energy is released in the form of heat to the surroundings.
Endothermic Enthalpy Change
∆H. the energy needed to break bonds is greater than the energy released when the new bonds form, so energy must be absorbed from the surroundings.
Bond energy
the amount of energy in kJ/mol that is needed to break one mole of a bond.
Fuels _______
contain stored chemical energy that is released, mainly in the form of heat (and sometimes light), when combusted (burned).
Fuel cell
an electrochemical cell that converts chemical energy from fuel into electricity. The hydrogen fuel cell uses hydrogen as its fuel.
Oxidation reaction at the hydrogen fuel cell
H 2 → 2H+ + 2e –
Reduction reaction at the hydrogen fuel cell
O 2 + 4H + + 4e – → 2H 2 O
Total Reaction at the hydrogen fuel cell
2H 2 (g) + O 2 (g) → 2H 2 O(g)
Advantages of Hydrogen fuel cells
- Hydrogen produces no carbon emissions, which is better for the environment.
- It has about the same energy content as petrol.
- A source of hydrogen is water, which is in plentiful supply.
Disadvantages of Hydrogen fuel cells
- Hydrogen is highly flammable and must be handled carefully.
- It is a gas and therefore has to be compressed for storage. This can be dangerous due to the risk of explosion.
- Most hydrogen comes from the reaction between hydrocarbons, such as methane, and steam. Methane (natural gas) is a fossil fuel and is a non-renewable energy source.