Chapter 5 Solutions Flashcards
Solution
Homogenous mixture of substances composed of at least one solute and one solvent. Uniform at the molecular level.
Heterogeneous Mixture
Contains particles large enough to block or scatter light waves. Opaque or translucent in appearence.
Homogenous Mixture
A mixture in which the proportion of each chemical in the sample remains the same, no matter how small the sample is.
Aqueous solution
Water is the solvent
Electrolyte
Compounds whose aqueous solutions conduct electricity
Nonelectrolyte
Compounds whose aqueous solutions do not conduct electricity
Dissociation
The separation of ions that occurs when an ionic compound dissolves in water
Ionization
The process by which a neutral atom or molecule is converted into an ion
Breaking existing bonds
Uses energy
Forming new bonds
Releases energy
What did Svante Arrhenius first explain
Electrolytes. He focused on why some aqueous solutions conduct electricity, but others do not.
What did Arrhenius propose in 1887?
When particles of a substance dissolve, they separate from each other and disperse into the solution. Nonelectrolytes disperse as electrically neutral particles. When ionic compounds dissolve, the individual ions separate. The charged particles explain the conductivity of the solutions.
What bonds may be broken in the dissociation of an ionic compound?
- Ionic bonds in a solid
- intermolecular forces between water molecules
The breaking of these bonds absorbs energy
What bonds may form in the dissociation of an ionic compound?
- electrostatic forces between ions and water molecules
The bond formed releases energy
Strong acids, three examples
Acids that are very good conductors. Sulfuric acid, nitric acid, hydrochloric acid are examples of very strong acids that are almost completely ionized when in solution.
Weak acids
Acids with low conductivity. Most common acids, such as acetic acid, are weak.
Solubility of nonpolar molecular compounds
Generally do not dissolve in water
Solubility of polar molecular compounds
May be Slightly soluble in water
Solubility of polar molecular compounds with hydrogen bonding
These types of bonds are most likely to be very soluble in water
Examples of molecular compounds with high solubility
- ammonia, NH3(g)
- hydrogen peroxide, H2O2(l)
- methanol, CH3OH(l)
- ethanol, C2H5OH(l)
- glucose, C6H12O6(s)
- sucrose, C12H22O11(s)
Examples of molecular compounds with low solubility
- methane, CH4(g)
- propane, C3H8(g)
- octane, C8H18(l)
Concentration
Ratio that compares the volume of solute to the quantity of solution.
Concentration = quantity of solute/ quantity of solution
Percentage by volume
Volume of a solute (mL) dissolved in every 100mL of a solution. expressed as %V/V
c = V solute/ V solution x 100%
Percentage weight (mass) by volume
Mass of a substance (g) dissolved in every 100mL of solution. Expressed as %W/V
c = m solute/ V solution x 100%
Percentage weight by weight (mass)
The mass of a solute (g) over the mass of a solution (g) times 100%. Expressed as %W/W
c = m solute/ m solution x 100%
Solubility of solids in water
Usually more soluble at higher temperatures.