chapter 5 - galvanic cells Flashcards
galvanic cells
an electrochemical cell where chemical energy is converted into electrical energy
done when reactants are separated, but kept in contact by a wire
features of galvanic cells
- two half cells
contains electrode (reducing agent) and electrolyte (oxidising agent) - wire
- salt bridge
labelling electrodes
oxidation at anode (negative electrode)
- negative because source of electrodes
reduction at cathode (positive electrode)
the cell with the better reducing agent is the anode (electrochemical series)
reducing agent - bottom right
oxidising agent - top left
types of half cells
metal/ metal ion
transition metal ion/ transition metal ion
non metal ion/ non metal
salt bridge
- only ions
- positive ions away from anode
- negative ions towards anode
cell voltage
V = E0 (oxidising half cell) - E0 (reducing half cell)
at SLC
primary cell
- not rechargeable
- go flat when equilibrium is reached
- named after electrolyte
secondary cell
- rechargeable
- products converted back to reactants
discharging vs recharding
discharging - secondary cell is producing electricity
electrons coming out of negative electrode (anode)
recharging - electrons are pushed back into the same electrode
anode gains electrons, reduction is occuring, now cathode