chapter 10 - organic chem Flashcards
structural isomers
compounds with the same molecular formula but different structures
- chain isomers
- positional isomers
alkanes
CnH2n+2
- ane
- non polar
- saturated
alkenes
C2H2n
- ene
- non polar
- unsaturated
alkynes
CnH2n-2
- yne
- non polar
- unstaurated
benzene
C6H6
- unsaturated
- 5 carbons, each has 3 bonds around it (2 C and 1 H) and 6 delocalised electrons in a ring
stereoisomers
- optical isomers
- geometric isomers
optical isomers
- mirror image of each other
- if there are four different groups on a C (chiral)
- two forms are not superimposable
- L and D
geometric isomers
- cis
- trans
haloalkanes
CnH2n+1X
add chloro-, bromo-, iodo-, floro-
name as alkane
alcohol
CnH2n+1OH
- ol
- hydroxyl group
- polar
primary alcohol - OH on terminal C
secondary alcohol - OH in C bonded to two other C
tertiary alcohols - OH on C bonded to three other C
amines
CnH2n+1NH2
- amine
- amino group
- polar
primary amine - NH2 bonded to one C
secondary amine - NH2 is bonded to 2 C
tertiary amine - NH2 is bonded to 3 C
carboxylic acids
Cn-1H2n-1COOH
- oic acid
- carboxyl group
- always on end
amino acid
NH2 + Cn-1H2n-1COOH
aldehydes
RCHO
- al
- carbonyl
- always on end
ketones
RCOR’
- one
- carbonyl
- in middle