Chapter 5 Flashcards
What do you call an ionic compound formed through the reaction of an acid and a base?
A salt.
Salts ____ in aqueous solution
dissociate.
Dissociated salt ions may do what to create a basic or acidic solution?
Hydrolyze (react w water)
What happens to a solution if neither the anion/cation hydrolyze?
Solution will be neutral.
What are the 3 rules for hydrolysis of a salt?
- cations in family 1 and 2 won’t hydrolyze.
- anions derived from a strong acid won’t hydrolyze.
- amphiprotic ions favour either basic or acidic hydrolyzation even though they can do both.
What are the 4 steps to seeing what the pH range of a salt in solution will be?
- write the dissociation equation
- will cation hydrolyze?
- Will anion hydrolyze?
- determine pH range.
How does oxygen affect acid strength?
The more oxygen atoms, the stronger the acid.
What do you call a solution that resists a change in pH when H+ or OH- is added?
A buffered solution.
What does a buffered solution contain?
- A weak base + salt containing its conjugate acid.
OR - A weak acid + salt containing its conjugate base.
What will the pH of the solution equal when [weak acid] = [conjugate base]?
The pH of solution = pKa
What governs the pH of a buffered solution?
the ratio of weak acid to conjugate base or weak base to conjugate acid
Addition of H+ to a buffered solution will:
consume conjugate base present
Addition of OH- to a buffered solution will:
consume conjugate acid present
What is the equivalence point in an acid-base titration?
mols H+ = mols OH-
What do you call a solution of known concentration?
Standardized solution.