Chapter 4.5 Oxidation - Reduction (redox) Reactions Flashcards
oxidation
the loss of electrons
reduction
the gain of electrons
oxidizing agent
the species doing the oxidizing (causing the electron loss)
reducing agent
the species doing the reducing (causing the electron gain)
oxidation number (oxidation state)
the charge the atom would have if electrons were transferred completely, not shared
General rules for assigning an oxidation number (O.N.) (3)
- For an atom in its elemental form, O.N. = O
- For a monoatomic ion, O.N. = ion charge (sign before numeral)
- The sum of O.N. values for the atoms in a molecule or formula unit of a compound equals zero. The sum O.N. values for the atoms in a polyatomic ion = the ions charge
Rules for Specific Atoms: Group 1A
O.N. = +1 in all compounds
Rules for Specific Atoms: Group 2A
O.N. = +2 in all compounds
Rules for Specific Atoms: Hydrogen
O.N. = +1 in combination w/ nonmetals O.N. = -1 in combination w/ metals and boron
Rules for Specific Atoms: Fluorine
O.N. = -1 in all compounds
Rules for Specific Atoms: Oxygen
O.N. = -1 in peroxides (two oxygens covalently bonded together, ex. H2O2) O.N. = -2 in all other compounds (except w/ Fluorine)
Rules for Specific Atoms: Group 7A
O.N. = -1 in combinations w/ metals, nonmetals (except O), all other halogens lower in the group