Chapter 4: Fire Dynamics Flashcards
Fire dynamics
describes the meeting point between fire science, material science, fluid dynamics of gases and heat transfer
Oxidizers
are not combustible but will support or enhance combustion
Using science to remain safe
o Identify fire dynamics
o Anticipate the next stages of the fire
o Anticipate how operations may impact fire behaviour
Physical science
is the study of matter and energy
Matter
physical materials that occupy space and have mass
A physical change
occurs when a substance remains chemically the same but changes in size shape or appearance
o ex: water freezing liquid to solid and boiling liquid to gas
Chemical reaction
when a substance changes from one type of matter into another such as two or more substances combining to form compounds
Oxidization
a chemical reaction involving the combination of an oxidizer such as oxygen in the air with other materials
o Can be slow such as the combination of oxygen with iron to form rust, or rapid, as the combustion of methane (natural gas) or an explosion
Energy :
Is the capacity to perform work
Work and In the case of heat
occurs when a force is applied to an object over distance or when a substance undergoes a chemical, biological, or physical change
in case of heat work means increasing a substances temperature
Potential energy
represents the amount of energy that an object can release at some point in the future
heat of combustion:
The potential energy available for release in the combustion process
o The rate at which fuel releases energy overtime depends on many variables including, chemical composition, arrangement, density of fuel, availability of oxygen for combustion
Kinetic energy
is the energy that a moving object possesses (releasing energy)
how does kinetic energy work
o When heat is introduced the molecules within the field begin to vibrate
o As the Heat (thermal energy) increases, these molecules vibrate more and more rapidly
There are many types of energy including
chemical, thermal, mechanical, electrical, light, nuclear, sound
All energy can
change from one type to another
Energy is measured in
joules
joule
international system of units (SI)
o The quality of heat required to change the temperature of 1 g of water by 1°C is 4.2 joules
British thermal unit (BTU):
customary system of measurement
o Is the amount of heat required to raise the temperature of 1 pound of water by 1°F
o 1055J= 1 BTU
Exothermic reactions
reactions that emit energy as they occur
o Fire is an exothermic chemical reaction that releases energy in the form of heat and sometimes light
Endothermic reactions
reactions that absorb energy as they occur
o Ex converting water to steam
Fire triangle and fire tetrahedron are used to
to explain the elements of fire and how fires can be extinguished
The fire triangle shows
three elements necessary for combustion to occur: fuel, oxygen and heat
o Remove any one of these elements in the fire will be extinguished
the fire tetrahedron model includes
the chemical chain reaction to explain flaming or gas phase combustion
o reducing agent (fuel)
o chemical chain reaction
o heat
o oxidizing agent
Fuels must be in a state to burn
Fuels must be in a gaseous state to burn
off gassing
When heat is transferred to a liquid or solid the substance as temperature increases in the substance starts to convert to a gaseous state
Pyrolysis
off gassing of solids
o Process/Chemical change of breaking down of a solid to a gas
o (solid fuel converted to gaseous fuel-lighter to wood off gases )
Vaporization:
physical change in liquids -off gassing of liquids (liquid converted to vapor)
Piloted ignition
occurs when a mixture of fuel and oxygen encounter an external heat source with sufficient heat or thermal energy to start the combustion reaction
o Most common form of ignition
Auto ignition
occurs without any external flame or spark to ignite the fuel gases are vapours
o The fuels surface is heated to the point at which the combustion reaction occurs (pyrolysis)
Autoignition temperature (AIT)
is the minimum temperature at which a fuel in the air must be heated in order to start self-sustained combustion
The autoignition temperature of a substance is always
The autoignition temperature of a substance is always higher than its piloted ignition temperature
Combustion
is a chemical reaction
There are two modes of combustion
non-flaming and flaming
Nonflaming combustion
occurs more slowly and at lower temperature producing a smouldering glow
o The burning may be localized on or near the fuel surface where it is in contact with oxygen
Flaming combustion and occurs when
produces a visible flame above the material surface
o occurs when a gaseous fuel mixes with oxygen in the correct ratio and heats to ignition temperature
Flaming combustion Requires
liquid or solid fuel to be converted to the gas phase
o When heated both liquid and solid fuels will emit vapours (pyrolysis) that mix with oxygen, gases ignite, producing flames above the material surface
The fire tetrahedron accurately reflects the conditions required for
required for flammable combustion
Each element of the tetrahedron must be in proper proportion and removing any element will interrupt the chemical chain reaction and stops flaming combustion
how does flaming combustion work
Ignition is where the combustion process begins. a heat source pyrolizes a fuel, creating fuel gases. Those glasses mix with oxygen and ignite creating fire
o As the heat transfers to the gasoues combustion products they expand and begin to rise and move away from the fire due to buoyancy
Products of combustion
as fuel burns its chemical composition changes which produces new substances
o Heat and smoke
Smoke
is the product of incomplete combustion
Incomplete combustion
is combustion that is incomplete when any of the fuel is left after combustion has occurred
Combustion is incomplete in a structure fire meaning that some of the fuel does not burn but instead gets entrained with hot gases and rises aloft
unburned fuel is smoke and has a potential to
burn
When the air supply is limited the level of incomplete combustion is
higher which produces more smoke
Most structure fires involve multiple types of fuel including
o Carbon-based fuels: wood, cotton
o Hydrocarbon fuels: plastics, synthetic fibers
- gases
Carbon monoxide
is a toxic product of the incomplete combustion of organic materials
Colorless, odourless gas present at almost every fire
CO combines with haemoglobin about 200 times more effectively than oxygen does
Hydrogen cyanide
toxic and formable substance produced in the combustion and materials containing nitrogen is also commonly found and smoke
Natural fibre such as wool, cotton, silk
Resin such as carbon fibre or fibreglass
Synthetic polymer such as nylon or polyester
Synthetic rubber such as neoprene silicone and latex
HCN is 35 times more toxic than CO
Prevents the body from using oxygen at the cellular level
Can be inhaled ingested or absorbed into the body where it then targets the heart and brain
Enters the bloodstream and prevents the blood cells from using oxygen properly killing the cells
Carbon dioxide
it’s a product of complete combustion of organic materials
Not toxic in the same way as CO or HCN displaces existing O2 creating an oxygen deficient atmosphere
Formaldehyde
- Colourless gas with a pungent irritating odour that is highly irritating to the nose
- 50-100 ppm can cause severe irritation to respiratory tract a serious injury
- Exposure to high concentrations can cause injury to the skin
- Formaldehyde is a suspected carcinogens
Nitrogen dioxide
- Reddish brown gas or yellowish brown liquid which is highly toxic and corrosive
Irritants in smoke
are substances that cause breathing discomfort and inflammation of the eyes, respiratory tract and skin
- Smoke contains significant amounts of unburned fuels in the form of solid and liquid particulates
Pressure
Is the force per unit of area applied perpendicular to a Surface
Standard temperature 68F 20c and atmospheric pressure gases…
remain calm and don’t move
Differences and pressure above or below standard atmosphere pressure,it creates
movement in gases
Gas always moved from areas of —-pressure to areas of —— pressure
Gas is always moved from areas of high-pressure to areas of low pressure
Heated gasses will
rise remain aloft and generally travel up and out
cooler fresh air will
generally travel inward toward the fire this exchange of air creates a convective flow
Heat release rate
total amount of heat released per unit time
The heat release rate is typically measured in kilowatts or megawatts
Heat
is the thermal kinetic energy needed to release the potential chemical energy in a fuel
how does heat work at the molecular level
o Heat vibrates fuel molecules
o Fuel changes from solid or liquid to gas
o The fuel emits flammable vapours which can ignite and release thermal energy
o Thermal energy heats uninvolved fuels
Temperature
is the measurement of heat
o Temperature is the measurement of average kinetic energy in the particles of a sample of matter
o Measured using several different scales
A dangerous misconception is that temperature…
is an accurate predictor for measurement of heat transfer
Heat flux
is a measure of heat energy transfer rate
o Measured in kilowatts per square meter
Heat transfer and PPE
temperature tells wether its safe to go in environment
o Heat transfer rate determines how long PPE will protect the firefighter in environment
Sources of thermal energy
- Chemical, electrical, and mechanical energy are common sources of heat that resukt in the ignition of a fuel
Chemical energy
oxidation
- Chemical energy: the most common source of heat in combustion reactions
The potential for oxidization exists when
any combustible fuel is in contact with oxygen
Self heating
a form of oxidation, is a chemical reaction that increases the temperature of a material without the additional external heat
Spontaneous ignition
which is ignition without the addition of external heat
For self heating to progress to spontaneous ignition, following factors are required:
o The insulation properties of a material immediately surrounding the fuel must be such that heat cannot dissipate as fast as it is generated
o The rate of heat production must be great to raise the temperature of the material to its autoignition temperature
o The available air supply in and around
rags soaked in linseed oil have a potential for spontaneous ignition because
the natural oxidization of this vegetable oil and the cloth will generate heat if some method of heat transfer such as air movement around the rags does not dissipate heat
o also charcoal and hay/manure
The rate of most chemical reactions increases as
temperature of the reacting materials increases
Electrical energy can generate temperatures
high enough to ignite any combustible materials near the heated area
Resistance heating
electric current flowing through a conductor produces heat
Overcurrent or overload
is unattended resistance heating
o when the current flowing through a conductor exceeds its design limits
arcing
the arc is a high temperature luminous electric discharge across a gap or through a medium such as charred insulation
Arcs may be generated when there is
a gap in the conductor such as a cut or frayed wire or when there is a high voltage, static electricity or lightning
Sparking:
when an electrical arc occurs, luminous (glowing) particles can form and splatter away from the point of arcing
Mechanical energy
friction and compression.
The movement of two surfaces against each other creates
heat of friction that generates heat and or Sparks
Heat is generated when a gas is…
because…
compressed
o When a compressed gas expands, the gas absorbs the heat
Heat transfer:
transfer of heat from one point or object to another is a part of the study of thermodynamics
Heat transfer warmer objects to cooler objects because
heated materials will naturally return to a state of thermal equilibrium
The greater the temperature differences between the bodies the greater the transfer rate
Thermal equilibrium
in which all areas of an object are a uniform temperature
- Objects at the same temperature do not transfer heat
Heat transfers from one body to another by three mechanisms
conduction, convection, and radiation
Conduction:
and occurs when:
is the transfer of heat through and between solids
- Occurs when the material is heated as a result of direct contact with the heat source
conduction Results from
increased molecular motion and collisions between a substances molecules, resulting in the transfer of energy through the substance
The more closely packed the molecules of a substance are…
the more readily it will conduct heat
Heat transfer due to conduction is dependent upon three factors:
o Area being heated
o Temperature difference between the heat source and the material being heated
o Thermal conductivity of the heated material
Insulating material
Good insulators are materials that
The best insulators are those made of
slow the conduction of heat from one solid to another
Good insulators are materials that do not conduct heat well because their physical make up disrupts the point-to-point transfer of heat or thermal energy
The best insulators are those made of particles or fibers will void spaces between them filled with a gas such as air
Convection
the transfer of thermal energy by the circulation or movement of a fluid (liquid or gas)
convection In the Fire environment
In the Fire environment, convection usually involves transfer of heat through the movement of hot smoke and fire gases
The heat flows from the hot fire gases to the cooler structural surfaces, building contents and air
convection occurs in what direction?
- Convection may occur in any direction
- Vertical movement is due to the buoyancy of smoke and fire gases
- Lateral movement is usually the result of pressure difference
Radiation
is the transmission of energy as electromagnetic waves,
Radiant heat
can become the dominant mode of heat transfer as the fire grows in size
- can have a significant effect on the ignition of objects located some distance from the fire
- Significant factor in the fire development and spread in compartments
- Numerous factors influence radiant heat transfers including:
o Nature of the exposed surfaces: dark coloured materials in it and absorb heat more effectively than light coloured materials; smoother highly polished surfaces reflect more radiant heat the rough surfaces
o Distance between the heat source in the exposed surface: increasing distance reduces the effect of radiant heat
o Temperature of the heat source: unlike other methods of heat transfer that depends on the temperature of both the heat source and exposed surface, radiant heat transfer primarily depends on the temperature of the heat source
radiated heat energy travels
radiated heat energy travels in a straight line at the speed of light
Radiation is a common cause of
Radiated heat travels through
Materials that reflect, absorb, or scatter radiated energy will
- Radiation is a common cause of exposure fires
- Radiated heat travels through vacuums and air spaces that would normally disrupt conduction or convection
- disrupt the heat transmission
Interaction among the methods of heat transfer
- The fire radiates heat, causes convection heat through hot fuel gases, and conducts heat through burning materials or metals that are involved in the fire
- Convected heat and radiated heat that reaches walls and ceilings heat still surfaces which begin to conduct heat to whatever extent possible based upon the materials thermal conductivity
- But heat us surface well then begin to radiate heat which could lead to ignition, combustion, convection and so on
Fuel
the oxidized or burn material or substance in the combustion process
o gas, liquid or solid
reducing agent
the fuel in a combustion reaction
o fuels may be inorganic or organic
inorganic:
organic
- inorganic: do not contain carbon
- organic: contains carbon
o most common fuels are organic
organic fuels can be divided into hydrocarbon based fuels such as:
o gasoline
o plastics
o fuel oil
o cellulose based materials (wood and paper)