Chapter 4 - Chemical Foundations: Elements, Atoms, and Ions Flashcards

1
Q

What are the 2 applications of chemistry that were used before 1000 BC?

A

the processing of ores to produce metals for ornaments and tools and the use of embalming fluids

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2
Q

What were the four fundamental substances that the Greeks had proposed matter to have composed of in 400 BC?

A

fire, earth, water, and air

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3
Q

Some alchemists were what?

A

mystics and fakes who were obsessed with the idea of turning cheap metals into gold

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4
Q

Which elements were found by alchemists?

A

mercury, sulfur, and antimony

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5
Q

What did alchemists learn how to do?

A

to prepare acids

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6
Q

Who was the first scientist to recognize the importance of careful measurements?

A

Robert Boyle (1627-1691)

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7
Q

What was Boyle’s most important contribution to science?

A

his insistence that science should be firmly grounded in experiments (his definition of element was based on experiments)

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8
Q

Why couldn’t air be considered an element?

A

because it could be broken down into many pure substances

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9
Q

All matter can be broken down chemically into about how many different elements?

A

100

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10
Q

How many different elements are known? And how many of those occur naturally?

A

115; 88

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11
Q

What are the 5 most abundant elements in the Earth’s crust, oceans and atmosphere? (List in order of abundance)

A

Oxygen (49.2%), silicon (25.7%), aluminum (7.50%), iron (4.71%), calcium (3.39%)

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12
Q

What are the elements that are the basis for all biologically important molecules?

A

Oxygen, carbon, hydrogen, and nitrogen

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13
Q

What are trace elements?

A

elements found in the body that are crucial despite their small amounts

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14
Q

how many known substances are composed of elements?

A

millions

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15
Q

What is the microscopic form of an element?

A

the single atom of the element

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16
Q

What is the macroscopic form of an element?

A

a sample of the element large enough to weigh on a balance

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17
Q

What does the law of constant composition state?

A

a given compound always has the same composition regardless of where it comes from

18
Q

State Dalton’s atomic theory (1808)

A

1) elements are made of tiny particles called atoms
2) all atoms of a given element are identical
3) the atoms of a given element are different from those of any other element
4) atoms of one element can combine with atoms of other elements to form compounds. A given compound always has the same relative numbers and types of atoms
5) atoms are indivisible in chemical processes. Atoms are not created or destroyed in chemical reactions. A chemical reaction simply changes the way the atoms are grouped together

19
Q

Who was J.J. Thomson?

A

showed that all types of atoms must contain negative particles or electrons; he also concluded that atoms contained positively charged particles to balance the electrons

20
Q

Who was William Thomson or Lord Kelvin?

A

introduced the plum-pudding model of an atom

21
Q

Who was Ernest Rutherford?

A

introduced the idea of a nuclear atom, contrary to the plum pudding model

22
Q

What is a nuclear atom?

A

atom with a dense center of positive charge (nucleus) surrounded by tiny electrons moving in empty space

23
Q

When did Rutherford conclude that the nucleus of the atom contained protons?

A

1919

24
Q

Who showed that nuclei contained neutrons?

A

Rutherford and James Chadwick (1932)

25
Q

What is the diameter of the nucleus of an atom?

A

10^ -13 cm

26
Q

What is the average distance of electrons from the nucleus?

A

10^ -8 cm

27
Q

The proton’s positive charge is equal to what?

A

the negative charge of the electrons

28
Q

Why do different atoms have different chemical properties?

A

the number and arrangement of electrons

29
Q

What accounts for most of the atomic volume?

A

The space in which the electrons move

30
Q

Which subatomic particle is in charge of intermingling when atoms combine to form molecules?

A

electrons

31
Q

The number of what greatly affects the way elements can interact with other atoms?

A

electrons

32
Q

What determines the atom’s chemical behavior?

A

the number of electrons

33
Q

The number of protons is always equal to the number of electrons. True or false?

A

true

34
Q

What are isotopes?

A

atoms with the same number of protons but different number of neutrons

35
Q

what is the atomic number?

A

The number of protons

36
Q

What is the mass number?

A

the sum of the number of neutrons and protons

37
Q

A free atom has what charge?

A

a net zero charge

38
Q

What is chemistry?

A

The study of matter and how it reacts

39
Q

What is a chemical?

A

A substance with known composition

40
Q

What is the average atomic mass?

A

The average of all the mass of the given element

41
Q

1 mole=

A

6.022*10^23 (atoms, molecules, units)

42
Q

1 mole=what part of the periodic table?

A

The average atomic mass (g)