Chapter 4 Flashcards

1
Q

The expansion and compression work in a piston-cylinder device

A

Moving boundary work (P dV work)

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2
Q

A process during which the system remains nearly in equilibrium at all times

A

Quasi-equilibrium process

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3
Q

Wb is positive for ____

A

Expansion

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4
Q

Wb is negative for ____

A

Compression

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5
Q

The work associated with a moving boundary is called _____

A

Boundary work

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6
Q

The boundary work done during a process depends…

A

On the path followed as well as the end states

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7
Q

The area under the process curve on a P-V diagram represents the _____

A

Boundary work

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8
Q

The area under the process curve on a P-V diagram is equal, in magnitude, to…

A

The work done during a quasi-equilibrium expansion or compression process of a closed system

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9
Q

The net work done during a cycle

A

The difference between the work done by the system and the work done on the system

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10
Q

What is the boundary work for a constant volume process?

A

Wb=0

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11
Q

Boundary work done during _____ is always zero

A

A constant volume process

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12
Q

Energy balance when sign convention is used

A

Heat input and work output are positive

Heat output and work input are menegative

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13
Q

Stationary system: energy balance

A

Q-W = change in U

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14
Q

Work done on the system

A

Negative

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15
Q

Work done by the system

A

Positive

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16
Q

Closed system undergoing a quasi-equilibrium process

A

P = constant process energy balance

Not valid for closed systems processes

17
Q

Expansion against a vacuum

A

Involves no work and no energy transfer

18
Q

The energy required to raise the temperature of the unit mass of a substance by one degree as the volume is maintained constant

A

Specific heat at constant volume (cv)

19
Q

The energy required to raise the temperature of the unit mass of a substance by one degree as the pressure is maintained constant

A

Specific heat at constant pressure (cp)

20
Q

The specific heat of a substance changes with _____

A

Temperature

21
Q

Cv and Cp are ____

A

Properties

22
Q

The change in internal energy with temperature at constant volume

A

Cv

23
Q

The change in enthalpy with temperature at constant pressure

A

Cp

24
Q

Cp is always greater than Cv. True or False?

A

True

25
Q

At low pressures, all real gases approach behavior, and therefore their specific heats depend on ____ only

A

Temperature

26
Q

The specific heats of real gases at low pressures are called ____

A

Ideal gas specific heats, zero-pressure specific heats (Cp0, Cv0)

27
Q

Specific heat ratios of monatomic gases

A

It’s value is essentially constant at 1.667

28
Q

Specific heat ratios for diatomic gases

A

1.4 at room temperature

29
Q

Specific heat ratio varies with _____

A

Temperature

30
Q

A substance whose specific volume (or density) is constant

A

Incompressible substance

Solids and liquids

Cv=Cp

Specific volumes remain constant

31
Q

Liquids at constant pressure

A

Heaters

32
Q

Liquids at constant temperature

A

Pumps