Chapter 3: Energy, Catalysis, and Biosynthesis Flashcards

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1
Q

allows the cell to precisely control its metabolism

A

catalysis

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2
Q

the sum total of all the chemical reactions it needs to carry out to survive, grow, and reproduce.

A

metabolism

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3
Q

Two opposing streams of chemical reactions occur in cells:

A
  • catabolic pathway
  • anabolic pathway
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4
Q

The breakdown foodstuffs into smaller molecules, thereby generating both a useful form of energy for the cell and some of the small molecules that the cell needs as building blocks.

A

catabolic pathway (catabolism)

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5
Q

It uses the energy harnessed by catabolism to drive the synthesis of the many molecules that form the cell.

A

anabolic pathway (anabolism) or biosynthesis

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6
Q

The universal tendency of things to become disordered is expressed in a fundamental law of physics called the ________.

A

second law of thermodynamics.

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7
Q

This law states that in the universe as a whole, or in any isolated system (a collection of matter that is completely cut off from the rest of the universe), the degree of disorder can only increase.

A

second law of thermodynamics

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8
Q

systems will change spontaneously toward those arrangements that have the greatest probability.

A

second law

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9
Q

The measure of a system’s disorder.

A

entropy

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10
Q

the _________ the disorder, the ________ the entropy

A

greater - greater

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11
Q

What law expresses “ systems will change spontaneously toward arrangements with greater entropy”?

A

second law of thermodynamics

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12
Q

A cell is not an _________ system.

A

isolated

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13
Q

the chemical reactions inside a cell must increase the __________ of the entire system

A

total entropy

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14
Q

According to the ______________, energy cannot be created or destroyed—but it can be converted from one form to another

A

first law of thermodynamics

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15
Q

a product of energy conversion

A

heat

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16
Q

How does solar energy enter the living world?

A

through photosynthesis

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17
Q

a process that converts the electromagnetic energy in sunlight into chemical-bond energy in cells.

A

photosynthesis

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18
Q

Give examples of photosynthetic organisms:

A

plants, algae, and some bacteria

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19
Q

In the first stage of photosynthesis, energy from sunlight is captured and transiently stored as chemical-bond energy in specialized molecules called _________.

A

activated carriers

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20
Q

In the second stage of photosynthesis, the activated carriers are used to help drive a ___________ process.

A

carbon fixation

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21
Q

In this process, sugars are manufactured from carbon dioxide gas (CO2).

A

carbon fixation process

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22
Q

In plants and animals, the chemical energy is extracted from food molecules by a process of ________.

A

gradual oxidation or controlled burning

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23
Q

The Earth’s atmosphere is about how much oxygen?

A

21%

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24
Q

In the presence of oxygen, the most energetically stable form of carbon is ______ and that of hydrogen is ______.

A

CO2; H2O

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25
Q

The step-wise process by which food molecules are broken down to produce energy is known as cell respiration.

A

cell respiration

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26
Q

This means the addition of oxygen atoms to a molecule.

A

oxidation

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27
Q

involves the removal of electrons from an atom

A

oxidation

28
Q

involves the addition of electrons to an atom

A

reduction

29
Q

the acceleration of the specific chemical reactions needed to sustain life

A

catalysis

30
Q

energy that must be acquired by a molecule to undergo a chemical reaction (for example a collision with other molecules)

A

activation energy

31
Q

a substance that can lower activation energy

A

catalyst

32
Q

the most effective catalyst

A

enzymes

33
Q

_________ reactions are reductions

A

hydrogenation reactions

34
Q

and the reverse ___________ are oxidations.

A

dehydrogenation reactions

35
Q

energy that can be harnessed to do work or drive chemical reactions

A

free energy

36
Q

Each enzyme binds tightly to one or two molecules, called ________.

A

substrates

37
Q

A substance that can lower the activation energy of a reaction is termed a ______________.

A

catalyst

38
Q

The useful energy in a system

A

free energy or G

39
Q

it measures the amount of dis- order

A

ΔG

40
Q

those that create disorder in the universe by decreasing the free energy of the system to which they belong;

A

Energetically favorable reactions

41
Q

they have a negative ΔG

A

Energetically favorable reactions

42
Q

they create order in the universe

A

Energetically unfavorable reactions

43
Q

they have a positive ΔG

A

Energetically unfavorable reactions

44
Q

___________ is increased when useful energy (harnessed) is dissipated as heat (useless).

A

Disorder

45
Q

useful energy; can be harnessed and drive a chemical reaction

A

Free Energy / G

46
Q

the difference in energy in reactant and product molecules

A

free energy chance / ∆G

47
Q

The ratio of substrate to product at this equilibrium point

A

equilibrium constant, K

48
Q

the energy released in the binding interaction

A

binding energy

49
Q

the energy is stored as chemical-bond energy in a set of __________

A

activated carriers

50
Q

energetically favorable reaction is used to drive an energetically unfavorable one, so that an activated carrier or some other useful molecule is produced.

A

coupled reaction

51
Q

he wondered how energy is transformed during chemical reactions in cells.

A

Otto Meyerhof

52
Q

a pioneer in the field of cell metabolism

A

Otto Meyerhof

53
Q

He recognized that between its initial entry in the form of food and its final dissipation as heat, a large amount of energy must be made available by a series of interme- diate chemical steps that allow the cell or organism to maintain itself in a state of dynamic equilibrium.

A

Otto Meyerhof

54
Q

He determined that working muscles give off heat, both as they contract and as they recover; further, he found that the amount of heat correlates with how hard the muscle is working.

A

Archibald “A.V.” Hill

55
Q

The most important and versatile of the activated carriers in cells.

A

ATP (adenosine 5ʹ-triphosphate)

56
Q

Any reaction that involves the transfer of a phosphate group to a molecule.

A

phosphorylation reaction.

57
Q

the most abundant activated carrier in cells.

A

ATP

58
Q

The ultimate source of energy for most living organisms

A

sun

59
Q

release energy by breaking down organic molecules, including foods, through oxidative pathways.

A

Catabolic reactions

60
Q

generate the many complex organic molecules needed by the cell, and they require an energy input.

A

anabolic reactions

61
Q

catalyze reactions by binding to particular substrate molecules in a way that lowers the activation energy required for making and breaking specific covalent bonds.

A

Enzymes

62
Q

govern all of the associations (and dissociations) that occur between macromolecules and small molecules in the cell.

A

Equilibrium constants

63
Q

carries high-energy phosphate groups

A

ATP

64
Q

carry high-energy electrons

A

NADH and NADPH

65
Q

provide the carbon skeletons for the formation of macromolecules.

A

food molecules