Chapter 3 Flashcards
Metabolic pathways
sequence of enzymes mediated reactions leading to the formation of a particular product
metabolic pathways can be?
- Linear
- circular
- Branched or all three
metabolism
Anabolic
Catabolic
- Sum of all chemical processes in the cell
- needs energy
- takes complex molecules and break them down into small molecules (release of energy)
Law of Thermodynamics
- 1st law - total energy in the universe is contant, energy is neither created nor destroyed
2nd law - universe is continually moving to an increased state of entropy (msome energy becomes unavailable to use).
3rd law as temperature approaches absolute zero, the entropy of a system approaches a costant minimum.
Entropy (S)
thermodynamic quantity that measures that amount of disorder within a system (higher S means ore disorder); unusable energy within a systems.
Two types of chemical reactions
- exergonic - loses energy, products have less energy than the starting substance(s).
- Endergonic - gains energy, products have more energy than the starting substance(s).
Energy coupling
idea that energy can be transformed
Enthalpy (H)
in thermodynamic systems, the measure of energy within a system; internal energy plus pressure x volume
Gibbs Free Energy (G)
the usable energy of a system that can be used to drive a reaction
In any system:
otal energy=usable energy + unusable energy
or:
enthalpy (H) = free energy (G) + entropy (S)
H= G + TS (T= absolute temperature)
Thus, usable energy is
G= H-TS
Redox reactions
transfer the energy of electrons
reduction
- A gain of one or more electrons or hydrogen atoms
oxidation
- the loss of or more electrons or hydrogens atoms