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LC Chemistry > Chapter 22 - Families of Organic Compounds > Flashcards

Chapter 22 - Families of Organic Compounds Flashcards

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1
Q

What is a tetrahedral carbon?

A

Carbon that has four single bonds

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2
Q

Chloroalkane

A

Compound in which one or more of the hydrogen atoms in an alkane molecule have been replaced by chlorine atoms

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3
Q

How do you name a chloroalkane?

A
  1. Select longest carbon chain
  2. Name after parent alkane
  3. Indicate number of chlorine atoms by prefixes
  4. Use numbers to indicate position
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4
Q

Uses of chloroalkanes

A
  • Chloroform was one of the earliest anaesthetics (trichloromethane)
  • Solvents: tipex, removes oil stains
  • CFCs
  • Paint stripper
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5
Q

Solubility of chloroalkanes

A
  • Non-polar molecule
  • Not soluble in polar water
  • Soluble in non-polar solutions
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6
Q

Intermolecular bonding of chloroalkanes

A
  • Rarely found in nature
  • Mostly liquid at room temperature
  • Low boiling point due to Van der Waals forces between molecules
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7
Q

What is the general formula for alcohols?

A

CₙH₂ₙ₊₁OH

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8
Q

What is the functional group of alcohols?

A

hydroxyl (hydroxide) group

-OH

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9
Q

Functional group

A

Atom or group of atoms which is responsible for the characteristic properties of an organic compound or series of organic compounds

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10
Q

How do you name an alcohol?

A
  1. Select longest chain of carbon atoms to which the -OH group is attached
  2. Name after parent alkane, but change -e to -ol
  3. Number from end that gives lowest value to the carbon attached to the -OH
  4. Indicate the position of -OH with a number e.g butan-2-ol
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11
Q

Primary alcohol

A

Carbon atom joined to the -OH group is attached to only one other carbon atom e.g ethanol

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12
Q

Secondary alcohol

A

Carbon atom joined to the -OH group is attached to two other carbon atoms e.g propan-2-ol

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13
Q

Tertiary alcohol

A

Carbon atom attached to the -OH group is attached to three other carbon atoms e.g 2-methylpropan-2-ol

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14
Q

What do industrial alcohols have in them to prevent consumption?

A

Have methanol as an additive (denaturing) plus a purple dye. e.g methylated spirits

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15
Q

Uses of ethanol

A
  • Only alcohol you can drink
  • Large quantities can cause coma, vomitting and death
  • Relaxes muscles and slows reactions
  • Is addictive and can lead to liver disease and brain damage
  • Perfumes, aftershaves, deoderant
  • Polishes, varnishes, dyes
  • Solvents
  • Fuel
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16
Q

What is the legal blood/alcohol limit for driving?

A

20mg per 100cm³ blood

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17
Q

Intermolecular bonding of alcohols

A
  • Higher boiling point than corresponding alkanes
  • Liquid at room temperature
  • Higher boiling point due to presence of polar -OH group which forms hydrogen bonds between alcohol molecules and requires more energy to break
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18
Q

Solubility of alcohols

A
  • Miscible with water due to both being polar → hydrogen bonds
  • Mix so well that distillation cannot separate effectively → have to use calcium oxide to dry out fully
  • Solubility decreases as chain gets longer as the man chain is non-polar even though the -OH is polar
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19
Q

What is a planar carbon?

A

When a carbon has less than four single bonds, and a double or triple bond

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20
Q

What is the functional group of aldehydes?

A

-CHO

O=C-H

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21
Q

How do you name aldehydes?

A

Named from alkanes
Name ends in -a
Functional group must be at the end of the carbon chain

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22
Q

What is the general formula for aldehydes?

A

CₙH₂ₙ₊₁CHO

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23
Q

Aldehyde uses

A

• Methanal (formaldehyde) dissolved in water is called formalin and is used in embalming

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24
Q

What is the only aldehyde that’s gas at room temperature?

A

methanal

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25
Q

What is the name of the aldehyde that smells like almonds?

A

benzaldehyde

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26
Q

Intermolecular bonding of aldehydes

A
  • Carbonyl group (C=O) is very strongly polar due to difference in electronegativity values
  • No hydrogen bonding exists as H is not bonded to an electronegative element
  • Permanent dipole-dipole exists between the O of one molecule and the C of another
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27
Q

Boiling points of aldehydes

A
  • Due to d-d bonds, boiling points are much higher than alkanes
  • Lower than corresponding alcohols as there is no hydrogen bonding
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28
Q

What are ketones?

A

Similar to aldehydes except the functional group is joined to two carbons, and is not at the end of the chain like aldehydes

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29
Q

How do you name ketones?

A

Names end in -one

30
Q

Uses of ketones

A
  • Butanone is a strong plastic liquid glue, designed for ABS plastics especially
  • Solvents
  • Nail polish remover
31
Q

Intermolecular bonding of ketones

A
  • C=O is polar, rest is non-polar

* dipole-dipole

32
Q

Solubility of aldehydes

A
  • Lower members soluble in both polar and non-polar
  • Soluble in water due to polar C=0 forming hydrogen bond with the H⁺ in water molecule
  • Solubility decreases as chain length increases
  • All aldehydes are soluble in non-polar solvents
33
Q

Boiling points of ketones

A
  • Higher boiling points than alkanes
  • Lower than alcohol
  • Due to d-d
34
Q

Solubility of ketones

A
  • Soluble in polar and non-polar for same reasons as aldehydes
  • As chain length increases solubility decreases
  • Longer chains only soluble in non-polar
35
Q

What is the functional group of carboxylic acids?

A

carboxyl functional group -RCOOH

36
Q

How do you name carboxylic acids?

A

ending in -oic acid

37
Q

What are carboxylic acids made up of?

A

A C-OH from an alcohol and C=O from an aldehyde or ketone

38
Q

Uses of carboxylic acids

A
  • Methanoic acid (formic acid) found in stings of nettles and ants
  • Ethanoic acid (acetic acid) in vinegar
  • Propanoic acid and benzoic acid are food preservatives
39
Q

What causes the smell of rancid butter?

A

butanoic acid

40
Q

What causes the smell of human sweat?

A

Mix of carboxylic acids

41
Q

What causes the smell of smelly socks?

A

butanoic acid

42
Q

Intermolecular bonding in carboxylic acids

A
  • Two hydrogen bonds are very strong (at room temperature)

* Form clusters called dimers

43
Q

Boiling point of carboxylic acids

A

High boiling point due to two hydrogen bonds

44
Q

Solubility of carboxylic acids

A
  • Short chains soluble in water (due to hydrogen bonding with the water molecules) and non-polar
  • Solubility decreases as the non-polar chain length increases
45
Q

What is the functional group of esters?

A

Just like carboxylic acids except the H on the -OH is replaced by R’ to give -OR’ (but there is still a C=O bond)

46
Q

How do you name an ester?

A

The original acid group changes from -oic to -anoate and the -R group that replaced the -H on the acid is listed as an alkyl substitute,

The carboxylic acid gives the main chain of the esters name and the alcohol gives the side chain

47
Q

Esterification

A

The formation of an ester. Made by reacting an alcohol with a carboxylic acid in the presence of a catalyst (usually concentrated sulfuric acid). It is an example of a condensation reaction

48
Q

Condensation reaction

A

Chemical reaction in which two molecules combine to form a larger molecule with the loss of a smaller molecule such as water

49
Q

Where does the single oxygen in the ester come from?

A

The alcohol, not the carboxylic acid

50
Q

Uses of esters

A
  • Smells in nature
  • Perfumes
  • Fats and oils
  • Used to make soap
  • Polyesters
51
Q

Bonding in esters

A
  • Permanent dipoles between O and C
  • O bonds with the C of another molecule
  • Van der Waals between the Hs of molecules
52
Q

Boiling point of esters

A
  • Medium boiling points

* Lower members are volatile

53
Q

Solubility of esters

A
  • Short chains are soluble in both

* Long chains not soluble in polar water but are soluble in non-polar

54
Q

Describe the arrangement of electrons in a benzene ring

A
  • Each carbon has four electrons in their outside shell - three in sigma bonds and one in pi
  • P orbitals all overlap with the orbitals next to them to form electron clouds above and below the plane
  • The six electrons are delocalised
  • This gives extra stability and the benzene doesn’t react like other alkenes do
55
Q

Delocalised electrons

A

Free to move around the full cloud; not restricted to any atom

56
Q

Is benzene a polar or non-polar molecule?

A

All the C-C bonds are the same length, hence benzene is non-polar planar molecule

57
Q

Uses of benzene

A
  • Organic solvent (but is carcinogenic so methylbenzene is used)
  • Aromatic compounds used in making dyes, detergents, insecticides, chemical indicators
  • Cocaine, heroin, aspirin, morphine, paracetamol
58
Q

What is the organic natural aromatic product in almonds?

A

Benzaldehyde

59
Q

What is the organic natural aromatic product in tea?

A

Caffeine

60
Q

What is the organic natural aromatic product in cigarettes?

A

Nicotine

61
Q

What is the organic natural aromatic product in poppies?

A

Opium

62
Q

What is the organic natural aromatic product in orange peel?

A

Limonene

63
Q

What is the organic natural aromatic product in cinchona trees?

A

Quinine

64
Q

What is the organic natural aromatic product in mould?

A

Penicillin

65
Q

Steam distillation

A

Separation process used to isolate compounds at temperatures below their decomposition temperatures. It is carried out by bubbling steam through the material and distilling off the immiscible liquids

66
Q

What is the main constituent of clove oil?

A

eugenol

67
Q

Emulsion

A

Dispersion of small droplets of one liquid in another liquid in which it is not soluble

68
Q

Principal of Steam Distillation

A

A mixture of two immiscible liquids boils at a temperature that is below the boiling point of each of the individual liquids. The hot mixture of water vapour (from the steam) and oil (from the plant) is passes through a condenser and the distillate collected contains a mixture of water and oil

69
Q

What colour is the emulsion that collects in the graduated cylinder at the end of the distillation in the clove oil experiment?

A

milky

70
Q

Liquid-liquid extraction

A

A technique in which two immiscble liquids (eg oil of cloves and water) are separated using a solvent (eg cyclohexane) in which one of the components of the mixture (in this case the clove oil) has slightly higher solubility than the other (in this case the water), i.e the organic component is removed from the emulsion by dissolving this organic component in an organic solvent

71
Q

Why is a white powder added into the conical flask containing the organic layer in the liquid-liquid extraction part of the clove oil experiment? What was this white powder

A

The magnesium sulfate forms clumps that stick to the sides and bottom of the conical. It is a drying agent and absorbs water

LC Chemistry (24 decks)

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