Chapter 21 Flashcards

1
Q

Line Notation Steps

A
  • omit symbols for C and H (when bonded to C)
  • each line is a bond
  • fill in H to give each C 4 bonds
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Alkanes

A

Hydrocarbons (can be saturated or unsaturated)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Saturated hydrocarbons

A

Only single bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Unsaturated hydrocarbons

A

Have multiple bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

hydrogenation

A

adding hydrogen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

dehydrogenation

A

taking away hydrogen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Properties of Alkanes

A
  • LDF only
  • low BP
  • insoluble in water (nonpolar)
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Naming Alkanes

A

Add suffix “-ane”
ex) methane, ethane, propane, butane, pentane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Naming Branches Alkanes (Steps)

A
  • find longest C chain, name the alkane
  • Name each branch (if alkane, end in ‘yl’ if halogen end in’o’
  • count # C the branch is on
  • # C-branchnamebasenameane
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Alkenes

A

hydrocarbon with at least one double bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Naming alkenes

A
  • same as alkanes
  • suffix “-ene”
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Alkyne

A

hydrocarbon with at least one triple bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Naming alkynes

A
  • same as alkanes
  • suffix “-yne”
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Naming multiple multiple bonds

A
  • prefix # of multiple bonds before ‘ene’ or ‘yne’
  • ex) 2,4-heptadiene
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Optical Isomers in hydrocarbons

A

when atom is bonded to 4 different groups

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Cyclic Hydrocarbons

A

‘cyclo’ prefix to denote ring structure

17
Q

Multiple bonds in cyclic hydrocarbons

A

The multiple bond will be in positions 1 and 2, so name accordingly

18
Q

Organic functional Groups
- carboxylic acid
- ester
- amide
- aldehyde
- ketone
- alcohol
- ether
- amine

A
  • carboxylic acid: O = C - OH
  • ester: O = C - O
  • amide: O = C - N
  • aldehyde: O = C - H
  • ketone: O = C
  • alcohol: -OH
  • ether: O
  • amine: N
19
Q

Aromatic compounds

A
  • very stable
  • contain alternating double bonds
20
Q

positive deviation

A

unfavorable (+/-) , higher VP than expected, lower H

21
Q

negative deviation

A

increased IMF, lower VP than expected, higher H

22
Q

Primary functional group

A

connected to one hydrocarbon / halogen

23
Q

Secondary functional group

A

connected to two hydrocarbons / halogens

24
Q

Tertiary functional group

A

connected to three hydrocarbons / halogens

25
Q

naming ethers

A
  • like alkanes
  • suffix ‘oxy’
26
Q

naming aldehydes

A
  • suffix ‘al’
27
Q

naming alcohols

A
  • suffix ‘ol’
28
Q

naming ketones

A
  • suffix ‘one’
29
Q

naming carboxylic acids

A
  • suffix ‘oic acid’
30
Q

naming esters

A
  • count #C in R group without the double bond and end in ‘yl’
  • count #C in R group with the double bond, end in ‘oate’
31
Q

naming amines

A
  • suffix ‘amine’ in longest chain
  • # C where attached to N
  • shorter chain ends in ‘yl’
  • use N instead of # if short chain is attached to N
32
Q

Alcohol + Carboxylic acid Condensation

A

= ester + H2O

33
Q

Amine + Carboxylic acid Condensation

A

= amide + H2O

34
Q

homopolymer

A

polymer with same monomer

35
Q

copolymer

A

polymer with diff. monomers

36
Q
A