Chapter 2: The Chemical Context of Life Flashcards

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1
Q

What are atoms?

A

are the smallest unit of matter/ make up living and non living matter

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2
Q

What does all matter consist of?

A

all matter consists of at least 1 chemical element

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3
Q

What is a chemical element?

A

a pure substance made up of only one type of atom.

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4
Q

List/give the organizational hierarchy of atoms, elements, and matter? What do atoms make up in terms matter?

A

atom>chemical element>matter
Atoms make up living/nonliving matter

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5
Q

Of all the elements of life, how many are actually found in living organisms? And what are they?

A

majority of the elements are not utilized by living organisms. 97% of the mass of most life is composed of Carbon, Hydrogen, Nitrogen, Oxygen, Phosphorus, and sulfur (HNOPS) A.K.A bulk elements

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6
Q

What are trace elements?

A

elements required for life and found in living organisms in very small amounts.

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7
Q

Give 5 examples of trace elements?

A

NA
Ca
Cr
CI
Sn

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8
Q

What defines an element? and what causes it to change?

A

an element is defined by its atomic number. adding a proton changes an element but adding any other subatomic particles doesn’t

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9
Q

What is the mass number and the formula for calculating it?

A

is the mass of the nucleus of an atom.
Mass #= P+N

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10
Q

What is an atomic mass or weight?

A

refers to the average total mass of all atoms of an element

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11
Q

What are electron orbitals? and how can they be envisioned?

A

3d regions around the nucleus of an atom where electrons can be found. (can be envisioned in 2D as energy shells)

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12
Q

What is the relationship of the energy of energy shells and their distance to the nucleus?

A

energy shells closer to the nucleus are lower in energy than distant shells.
Distant shells are typically higher in energy, more reactive, and the ones that form chemical bond

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13
Q

What are valence electrons?

A

electrons found in the outermost shell energy shell (valence shell)

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14
Q

What is a neutral net charge?

A

when the # of Ps balances out with the # of Es

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15
Q

What is the octet rule?

A

states that atoms are stable (less reactive) when their valence shells are fully occupied.

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16
Q

How many electrons can a each shell hold?

A

1st energy shell: a max of 2 electrons
2nd: a max of 8 electrons
shells beyond that: varying #

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17
Q

What is an isotope?

A

are atoms of the same element that only vary in the # of neutrons.

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18
Q

What does an isotope have in terms of atomic number and mass number?

A

the same atomic number, but different mass numbers

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19
Q

What is atomic mass?

A

overall mass of an atom taking into account isotopes, which are very small and not expressed as an integer.

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20
Q

What are isotopes?

A

different forms of the same element with the same P but different N

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21
Q

How many isotopes are present in Carbon 12 (natural carbon)? and which is the most abundant?

A

There are 3 isotopes in carbon 12 with carbon 12 itself is 99% of carbon isotopes where the number of P and N are similar.

22
Q

What is true about carbon 13 and 14?

A

carbon 13 and 14 have the same number of protons but a different # of neutrons.

23
Q

Why is carbon 12 considered an isotope even though it has the same # of protons and neutrons?

A

isotopes are defined based on their differences in neutrons relative to the same element, not necessarily number of neutrons compared to protons.

24
Q

Explain the concept of Isotope (Carbon 12)?

A

concept of isotopes doesn’t require the # of neutron/protons to be different, it only requires the # of neutrons to vary while the same number of protons stay constant. It is not unique in being an isotope as they are defined y the variability of neutrons, not the quantity of protons/neutrons.

25
Q

What are radioactive isotopes?

A

unstable isotopes that break down and emit energy in the form of rays or particles.

26
Q

What is a half-life?

A

the time it takes for half of the radioactive atoms in a sample to break down at a pretty consistent rate.

27
Q

What determines the stability of an atom?

A

While the # of N play a role in determining whether an isotope is radioactive or not, it is the overall balance of N and P that determines the stability of an atom.

28
Q

What happens to energy during in a radioactive atom, and what is the purpose?

A

in a radioactive atom, energy and subatomic particles are released to reach a more stable state by emitting radiation.

29
Q

List the stability of Carbon and its isotopes?

A

Carbon 12 and 13= stable
Carbon 14= unstable because it has an unstable nucleus with too many neutrons compared to its protons,

30
Q

What causes stability to an atom?

A

equal or relatively similar # of protons and neutrons

31
Q

What are chemical bonds?

A

attractive forces between atoms, holding them together to form molecules and compounds.

32
Q

Define the following:
1. Molecules:
2. Compounds:

A
  1. substance containing 2 or more chemically bound atoms (atoms can be of same or different element)
  2. a complicated molecule of 2 different elements(atoms of different elements bonded together, and must consist of different elements)
33
Q

What is rule of saying regarding molecules and compounds?

A

all compounds are molecules but not all molecules are compounds

34
Q

What does a chemical formula reveal?

A

reveals the # and type of atoms in a molecule and help simplify structures

35
Q

Define the following terms:
1. Intermolecular bonds:
2. Intramolecular Bonds:

A
  1. interactions between atoms of DIFFERENT molecules
  2. interactions between atoms of the same molecule
36
Q

Are all molecules going to be classified as either intra or intermolecular?

A

no, because these terms specifically refer to the forces/ interactions happening rather than the molecule itself. Examples of these forces include ionic, covalent bonds, etc.

37
Q

What are covalent bonds?

A

an interaction between 2 atoms resulting from the equal sharing of electrons

38
Q

What are the two types of covalent bonds and why do these exist?

A

the two types of covalent bonds are polar and non-polar and they exist due to differences in the atom’s electronegativity.

39
Q

What is electronegativity?

A

it is a measure of an atom’s attraction to electrons or how hard these atoms pull on electrons. (measure on a scale of 0-4)

40
Q

What is the range of electronegativity on the periodic table?

A

It starts from low with hydrogen and increases in electronegativity as you reach oxygen which is one of the most electronegative elements

41
Q

What are non-polar covalent bonds?

A

have an equal sharing of electrons between atoms due to their relatively similar electronegativities. There is an equal force being applied to each side and therefore ends up in a nonpolar covalent bond

42
Q

What causes non- polar covalent bonds?

A

atoms of equal or similar electronegativities

43
Q

What are polar covalent bonds?

A

unequal sharing of electrons between atoms (due to different electronegativities) which leads to unequal distribution of electrons between atoms resulting in partial charges. (δ)

44
Q

What is a partial charge when it comes to polar covalent bonds?

A

because the electrons spend more time closer to one atom, that atom gains a partial negative charge (denoted as δ-). Conversely, the other atom, having electrons pulled away from it, gains a partial positive charge (denoted as δ+).

45
Q

What are Non-covalent bonds and what are some examples?

A

interactions between 2 atoms resulting from full or partial charges. Examples include ionic, and hydrogen bonds

46
Q

Define the following:
Partial charge:
Full charge:

A
  1. Occurs when electrons are not completely transferred but are shared unequally in a covalent bond. This results in a slight negative charge (δ-) on the more electronegative atom and a slight positive charge (δ+) on the less electronegative atom.

2.Refers to the complete gain or loss of electrons, resulting in ions. For example, Na+ has lost an electron to become positively charged, while Cl- has gained an electron to become negatively charged.

47
Q

What are ions?

A

are atoms or molecules with a net electrical charge that have either a positive or negative charge due to the gain or loss of electrons

48
Q

Define the following, and their charges?
Anions:
Cations:
Neutral:

A
  1. are - charged ions resulting from a + of an electron.
    • charged ions resulting from a - of an electron.
  2. When the # of electrons= the # of protons.
49
Q

What are ionic bonds?

A

electrical attractions between oppostiely charged ions. involves the TRANSFER of Electrons which van fill the valence shells of both atoms and create charges.

50
Q

What does the difference in electronegativity cause for?

A

A big difference in electronegativity= transfer of electrons which causes ionic bonds
Small difference or equal= share electrons which causes a covalent bond.

51
Q

What are hydrogen bonds? and what are some of their qualities?

A

interactions between a highly electronegative atom (F, O, or N) and a hydrogen atom.
weak individually but can be very strong together.

52
Q

Are F, O, and N the only elements that participate in a Hydrogen bond?

A

no they are not the only ones, but they are the primary elements that particpate in creating an H Bond.