Chapter 2 Chemical Components of Cells Flashcards
Methyl group
-CH3
- non polar hydrocarbon
Hydroxyl Group
-OH
-alcohols
Carboxyl Group
-COOH
-weak acid
Carbonyl Group
C=O
Carbonyl Group Types
- Ketone
-Aldehyde
Ketone
internal carbon
Aldehyde
terminal carbon
Amino Group
-NH2
- weak base
Amide Group
O=C-NH2
- carboxyl+amine
Phosphate Group
-PO3
ester and anhydrides
Sulfhydryl Group
-SH
- forms disulfide bonds
Hydrocarbons
-nonpolar
- don’t form hydrogen bonds
-generally insoluble in water
How do amines react in water?
combine with H+ ion to become positively charged
How do amides react in water?
amides are uncharged in water
Acid Anhydride
phosphate+carboxyl group
- high energy bond
Phosphoanhydride Bond
-found in ATP
- high energy bond
Top 3 contributors to the weight of a cell
- Water
- Macromolecules
- Phospholipids
Carbohydrates
-monosaccharides make up polysaccharides
- general formula (CH2O)n
Function of polysaccharides
- stores of chemical energy
- durable biological structural materials
Beta-glucose structure and pattern
down up down up ( OH groups)
Alpha glucose structure and pattern
down up down down ( OH group)
condensation
- water is released
- create macromolecules
- anabolic reaction
hydrolysis
-water is consumed
- breaks down macromolecules
- catabolic process
Glycosidic Bond
bond between carbon 1 and carbon 4 of another sugar
Maltose
Glucose + Glucose
Sucrose
Glucose + Fructose
Starch
1-4 linkage of 4 alpha glucose molecules
Cellulose
1-4 linkage of 4 beta glucose molecules
- oxygens alternate up and down
Fatty Acids and Lipids
- insoluble in water
- formed by condensation reactions
Fatty Acid and Lipids Function
- Structural: cell membranes
- Energy Storage: triacylglycerols.
Fatty Acids
long, unbranched hydrocarbon chains with single carboxyl group on the end
- amphipathic
- typically an even # of carbons
How do fatty acids act in water ?
either form a surface film or form a small micelle
How are fatty acids stored as an energy reserve
through an ester linkage to glycerol which forms triacylglycerol (fat)
Unsaturated Fat
cis double bond which causes bending
- not solid at room temperature
cis double bond
hydrogens are on the same side
trans fat
hydrogen on opposite sides
Effect of high trans fats
- membrane becomes less fluid
- clog arteries
Amino Acid Example of a polar group
serine
Hydrocarbon tails formula
-(CH2)n-CH3
Function of Amino Acids and Proteins
- Enzymatic
-Signaling
-Structural
Amino Acids
Monomer subunit of proteins
20 amino acids
Where does amino acid functionality come from
side groups
- acidic or basic
-polar or nonpolar
MEMORIZE STRUCTURE OF AMINO ACIDS
amino group + side chain+ carboxyl group
Nucleotides and Nucleic Acids
- DNA and RNA
- formed by condensation reactions
Function of Nucleotides and nucleic acids
- nucleotides function as energy carriers
- nucleotides function as signaling molecules
- DNA and RNA function to store and transmit( express) genetic information
Nucleotide
base+pentose+phosphate
Nucleoside
base + pentose
Phosphodiester linkage
joins nucleotides to form nucleic acids
- condensation reaction
Structural polarity of Nucleic acids
5’ end - free phosphate group
3’ end - free hydroxyl group
Watson and Crick
DNA is a double helix
antiparallel
10.5 bases/ turn
A +T or U
- two hydrogen bonds
- less stable
G + C
- three hydrogen bonds
- more stable
Purines
adenine and guanine
Pyrimadines
Thymine, Uracil , Cytosine
DNA Sugar
2- Deoxyribose
RNA Sugar
Ribose
DNA Function
Genetic information storage
RnA function
Genetic Expression, storage
what specifies structure
non covalent bonds and intramolecular interactions