Chapter 18-20 Flashcards
Reaction assumptions
Reactions are spontaneous: nothing can predict whether given substances will react
Reactions are fast: for a reaction to be useful it must occur within a reasonable time
Reactions are quantitative: is more than 99% complete, at least one reactant is completely used up, a reaction goes until completion
Reactions are stoichiometric: there is a simple whole number ratio of chemical amounts (moles) of reactants and products
Writing net ionic equations
Cancel identical entities that appear on both reactant and product sides, when cancelling spectator ions they must be identical in every way (# of miles, form, and state)
Review of chemical reactions
Formation= element> compound
Decomposition=compound>
element
Single replacement: element+compound >element+compound
Double replacement: compound+compound >compound+compound
Combustion: substance+ oxygen> common oxides
Mole ratio
Multiply the known amount of moles by the unknown molar coefficient and divide by the known molar coefficient
N* n unknown/ n known
Percent yield
Evaluates the overall experiment, is the ratio of the actual or experimental quantity of product obtained to the theoretical yield obtained from stoichiometry calculation
Percent yield=actual yield/ predicted yield x100
Common sources of experiment uncertainty
All measurements
Purity of the grade of chemical used
Washing precipitate(fine particles may be lost)
Qualitative measurements(estimations that affect measurements)
Stoichiometry
The description of the relative quantities of the reactants and products by chemical amounts (moles)
Gravimetric stoichiometry
The procedure for calculating the masses of reactants and products in a chemical reaction, chemical amount calculations are made from mass measurements
Gas stoichiometry
Stoichiometry is extended to gases using gas volume, pressure, temperature, molar volume, and ideal gas law
Solution stoichiometry
The application of stoichiometric calculation principles to solutions
Chemical reactions do not explain
Pressure and temperature conditions
Progress and process of a reaction
Measurable quantities
Quantitative reaction
One that is more than 99% complete
Stoichiometric reaction
There is a simple whole number ratio of chemical amounts of reactants and products
Net ionic equation
A chemical reaction equation that includes only reacting entities (molecules, atoms, ions) and omits any that do not change
Spectator ion
An ion that is present but does not take part in a chemical reaction