Chapter 13/14 Solution Chemistry Flashcards

0
Q

Describe particle size and shape for heterogeneous mixtures

A

There is no uniform shape and size

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1
Q

Define heterogeneous mixture and give EX’s

A

2 or more clearly different compunds

Ex: chex mix, raw milk

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2
Q

Define homogeneous mixture and give Ex’s

A

2 or more different substances in a single phase with uniform composition
Ex: saltwater, kool aid

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3
Q

What is another term for homogeneous mixture?

A

Soln

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4
Q

Define solution

A

Homogeneous mix of 2+ substances in a single phase

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5
Q

What do soln’s include?

A

Atoms, ions, molecules dispersed in one phase with same properties throughout

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6
Q

Particle size of solns

A

.01-1 nm

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7
Q

Define solute

A

Dissolved, lesser amnts

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8
Q

Define solvent

A

Does the dissolving, greater amnts

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9
Q

What makes up any soln?

A

Any s, l, g dissolved in any other s, l, or g

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10
Q

Define suspension and give Ex’s

A

When particles of a solid are too large to dissolve and they settle
Ex: muddy water, OJ with pulp

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11
Q

Particle size of suspensions

A

1000+ nm

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12
Q

Define colloid

A

When particles of solvent are too big to dissolve, but too small to settle out

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13
Q

Particle size of colloid

A

1-1000 nm

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14
Q

What does solvent become with respect to colloid?

A

Dispersing Medium

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15
Q

What does solute become with respect to colloid?

A

Dispersed phase

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16
Q

Ex’s of colloids

A

Mayo, smoke, fog, smog, gel

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17
Q

What is Tyndall effect use for?

A

Determine difference between colloid and soln

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18
Q

What will a colloid do that a soln wont?

A

Scatter light

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19
Q

Define electrolyte and give Ex’s

A

Dissolve in soln to produce ions an will support electrical current, usually ionically bonded
Ex: NaCl

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20
Q

Define non-electrolyte and give Ex’s

A

Dissolve in soln but dont support electrical current, usually covalently bonded
Ex: sugar

21
Q

Why happens to acids in Aq solns?

A

Ionize and support electrical current

22
Q

Why do acids do this?

A

Because they are very polar molecules

23
Q

Why wont pure water conduct electricity?

A

Only 2 molecules out of every billion ionize

24
Describe the number of charges in an ionic soln
Always an equal number
25
Describe the number of particles in an ionic soln
Not always equal
26
What 3 factors affect rte of dissolution?
Increased surface area, agitation, and change in T
27
How is increased surface area achieved?
Grinding or crushing solute into finer particles
28
How is agitation achieved?
Stirring/shaking the solvent/solute
29
How will the change in T of solvent increase rate of solution?
Make collisions more energetic and frequent. Some dissolve better in cold T
30
Define sat'd soln
One that has dissolved the maximum amnt of solute that it can for its T and V
31
Define unsaturated soln
One that can still dissolve more solute for its T and V
32
Define supersaturated soln
One thats forced to dissolve more than it should be for a given T and V
33
How can you achieve a supersaturated soln?
Heating
34
Describe stability if supersaturated soln
Unstable
35
Define solubility
Amnt of solute that'll form a saturated solution
36
What is like dissolves like based on?
Similarity of bonds, polarity, and intermolecular forces
37
What is dissociation?
Separation of ions in soln
38
What causes dissociation in water?
Addition of ionic solutes
39
What is the limit of a saturated soln?
When no particles of h2o are available to form spheres of solvation
40
When do the effects of P in solubility occur?
When solns have gas in them
41
Define Henry's law
Solubility of a gas in a liquid increases with increasing P and decreases with decreasing P
42
Define effervescence
Escape of a gas from a liquid in which it is dissolved
43
What does increased T of a gas in liquid do to solubility?
Causes decrease of solubility
44
What does change of T of a solid in liquid do to solubility?
Increase in T usually increases solubility but the opposite is true for some
45
When do solvation spheres form til?
All ions are hydrated
46
How does a soln become sat'd?
All ions will be hydrated
47
What do nonpolar solvents dissolve?
Fats, oils, greases
48
Define miscible and give Ex's
2 or more mutually soluble liquids | Ex: vinegar/water milk/coffee
49
Define immiscible and give Ex's
2 or more mutually insoluble liquids | Ex: oil/water oil/vinegar