Chapter 12: Properties of Water Flashcards

1
Q

What is the shape and type of bonding that a water molecule has?

A

V-shaped, contains polar covalent bonds

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2
Q

Why are water molecules polar?

A

An overall dipole exists as a result of the unsymmetrical nature of the polar O-H bonds, and the difference in electronegativity of oxygen and hydrogen

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3
Q

What are the strength of the forces that attract water molecules to each other?

A

As a result of the bonds between hydrogen and oxygen, the forces that attract water molecules to each other are strong hydrogen bonds

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4
Q

How many bonds can water molecules form with other water molecules?

A

Each water molecule can form up to four hydrogen bonds with other water molecules

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5
Q

What does the strength of the hydrogen bonds of water mean in terms of energy required to disrupt these bonds?

A

Relatively large amounts of energy are required to disrupt the bonds and seperate the molecules from each other, giving water relatively high melting and boiling points

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6
Q

What is the trend in boiling and melting point of group 16 hydrides?

A

They increase down the group, due to the increasing strength of dispersion forces

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7
Q

What is the exception in the trend of group 16 hydrides?

A

Water has significantly higher melting and boiling points due to its strong hydrogen bonds

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8
Q

Why is ice less dense than liquid water?

A

Its unique geometric arrangement of water molecules in a rigid, hexagonal structure with definite gaps, as a result of hydrogen bonding

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9
Q

What is heat capacity defined as?

A

A measure of a substance’s capacity to absorb and store heat energy

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10
Q

What does the specific heat capacity of a substance measure?

A

The quantity of energy in joules needed to increase the temperature of 1 gram of substance by one degree Celsius

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11
Q

Why is the specific heat capacity of water relatively high?

A

Due to the ability of the hydrogen bonds between water molecules to absorb and store heat energy

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12
Q

What is the correlation between grams and millilitres?

A

The mass of a sample of liquid water in grams is equal to its volume in millilitres

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13
Q

How can the heat energy required to increase a given mass of substance by a particular temperature be calculated?

A

Heat Energy (joules) = Specific Heat Capacity x Mass of Substance x Temperature Change

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14
Q

What is latent heat?

A

The energy absorbed by a fixed amount of substance as it changes state from a solid to a liquid or a liquid to a gas, which does not result in a change in temperature

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15
Q

What is the latent heat of vaporisation of a substance?

A

The heat energy required to change 1 mole of the substance from a liquid to a gas at its boiling point

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16
Q

What is the latent heat value of water compared to other similar molecules?

A

It has very high latent heat values due to its strong hydrogen bonding

17
Q

What is the latent heat of fusion of a substance?

A

The heat energy required to change 1 mole of the substance from a solid to a liquid at its melting point

18
Q

What are the latent heat of vaporisation and fusion values of water?

A

Latent heat of vaporisation = 44.0 kJ mol-1 (HIGHER)

Latent heat of fusion = 6.0 kJ mol-1 (LOWER)

19
Q

What is the significance of the relatively high latent heat of vaporisation of water?

A

The cooling effect of water on organisms is efficient and little water is lost, preventing cells from overheating